1,3-双(2,4,6-三甲基苯基)-2-咪唑烷亚基合成路线 （共 11 条）
反应条件
potassium hydride in tetrahydrofuran
T=25°C; 3 h;
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
in benzene-d6
T=60 - 100°C;
参考文献
Nyce, Gregory W.; Csihony, Szilard; Waymouth, Robert M.; Hedrick, James L.
Chemistry - A European Journal, 2004 , vol. 10, # 16 p. 4073 - 4079
反应条件
1: 71 percent / glac. AcOH
2: 65 °C
3: various solvent(s); benzene-d6 / 60 - 100 °C
View Scheme
参考文献
Nyce, Gregory W.; Csihony, Szilard; Waymouth, Robert M.; Hedrick, James L.
Chemistry - A European Journal, 2004 , vol. 10, # 16 p. 4073 - 4079
反应条件
1: 80 percent / propan-1-ol; H2O / 23 - 60 °C
2: 85 percent / sodium borohydride / tetrahydrofuran
3: 80 percent / formic acid / Heating
4: 72 percent / KH / tetrahydrofuran; various solvent(s) / 3 h / 23 °C
View Scheme
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
1: 85 percent / sodium borohydride / tetrahydrofuran
2: 80 percent / formic acid / Heating
3: 72 percent / KH / tetrahydrofuran; various solvent(s) / 3 h / 23 °C
View Scheme
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
1: 80 percent / formic acid / Heating
2: 72 percent / KH / tetrahydrofuran; various solvent(s) / 3 h / 23 °C
View Scheme
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
1: 65 °C
2: various solvent(s); benzene-d6 / 60 - 100 °C
View Scheme
参考文献
Nyce, Gregory W.; Csihony, Szilard; Waymouth, Robert M.; Hedrick, James L.
Chemistry - A European Journal, 2004 , vol. 10, # 16 p. 4073 - 4079
反应条件
potassium tert-butylate in tetrahydrofuran
0.5 h; Inert atmosphereSchlenk technique;
参考文献
Li, Haoquan; Misal Castro, Luis C.; Zheng, Jianxia; Roisnel, Thierry; Dorcet, Vincent; Sortais, Jean-Baptiste; Darcel, Christophe
Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 8045 - 8049
Angew. Chem., 2013 , vol. 125, # 31 p. 8203 - 8207
反应条件
1: sodium tetrafluoroborate; potassium carbonate; N-ethyl-N,N-diisopropylamine / toluene; dichloromethane; acetone; water / 1 h / 120 °C / |Heating; |Inert atmosphere
2: sodium hexamethyldisilazane / tetrahydrofuran / 20 °C / |Inert atmosphere
View Scheme
参考文献
Kolychev, Eugene L.; Asachenko, Andrey F.; Dzhevakov, Pavel B.; Bush, Alexander A.; Shuntikov, Viacheslav V.; Khrustalev, Victor N.; Nechaev, Mikhail S.
Dalton Transactions, 2013 , vol. 42, # 19 p. 6859 - 6866
反应条件
in hexane
T=23°C; Addition; 80 h;
参考文献
Arduengo III, Anthony J.; Calabrese; Davidson, Fredric; Rasika Dias; Goerlich, Jens R.; Krafezyk, Roland; Marshall, William J.; Tamm, Matthias; Schumtzler, Reinhard
Helvetica Chimica Acta, 1999 , vol. 82, # 12 p. 2348 - 2364
