1: (R)-1-bromo-2-methylpentane With magnesium in diethyl ether
2: oxirane in diethyl ether
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1.1: pyridine / 4 h
2.1: 6.3 g / LiBr / dimethylformamide / 20 °C
3.1: Mg / diethyl ether
3.2: diethyl ether
View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1.1: 5.6 g / LiBr / dimethylformamide / 20 °C
2.1: Mg / diethyl ether
2.2: diethyl ether
View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1.1: 6.3 g / LiBr / dimethylformamide / 20 °C
2.1: Mg / diethyl ether
2.2: diethyl ether
View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1.1: 7.2 g / methanol; p-toluenesulfonic acid
2.1: pyridine / 4 h
3.1: 5.6 g / LiBr / dimethylformamide / 20 °C
4.1: Mg / diethyl ether
4.2: diethyl ether
View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1.1: 6.8 g / methanol; p-toluenesulfonic acid
2.1: pyridine / 4 h
3.1: 6.3 g / LiBr / dimethylformamide / 20 °C
4.1: Mg / diethyl ether
4.2: diethyl ether
View Scheme
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1: (S)-1-bromo-2-methylpentane With magnesium in diethyl ether
2: oxirane in diethyl ether
参考文献
Tai, Akira; Syouno, Emi; Tanaka, Kazuki; Fujita, Morifumi; Sugimura, Takashi; Higashiura, Yasutomo; Kakizaki, Masashi; Hara, Hideho; Naito, Tikahiko
Bulletin of the Chemical Society of Japan, 2002 , vol. 75, # 1 p. 111 - 121
1: KOH; diethyl ether / Trennung der Isomeren durch Destillation und durch Krystallisation aus verschiedenen Loesungsmitteln
2: H3PO4
3: PtO2; glacial acetic acid / Hydrogenation
View Scheme
参考文献
Nasarow; Wercholetowa
Zhurnal Obshchei Khimii, 1948 , vol. 18, p. 1085
Chem.Abstr., 1949 , p. 1333
