(3,3-二甲基丁基)苯合成路线 （共 33 条）
反应条件
zirconocene dichloride in diethyl ether; benzene
Ambient temperature;
参考文献
Negishi, Ei-ichi; Miller, Joseph A.; Yoshida, Tadao
Tetrahedron Letters, 1984 , vol. 25, # 32 p. 3407 - 3410
反应条件
1: 2.) DAST / 1.) ether, 0 deg C; 2.) CH2Cl2, -78 deg C to 20 deg C
2: 70 percent / CH2Cl2 / 0.5 h / -78 °C
View Scheme
参考文献
Ooi, Takashi; Uraguchi, Daisuke; Kagoshima, Naoko; Maruoka, Keiji
Tetrahedron Letters, 1997 , vol. 38, # 32 p. 5679 - 5682
反应条件
potassium tert-butylate in dimethyl sulfoxide
T=20°C; 3 h; Inert atmosphereDarkness;
参考文献
Oksdath-Mansilla, Gabriela; Penenory, Alicia B.
Journal of Physical Organic Chemistry, 2011 , vol. 24, # 12 p. 1136 - 1143
反应条件
1: With iron (+/-)-(N,N'-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamine)dichloride in tetrahydrofuran
T=-20°C; 0.25 h;
2: With LiH3BNMe2 in tetrahydrofuran
T=-20 - 20°C; 16 h;
参考文献
Le Bailly, Bryden A. F.; Greenhalgh, Mark D.; Thomas, Stephen P.
Chemical Communications, 2012 , vol. 48, # 10 p. 1580 - 1582
反应条件
sodium tetrahydroborate in methanol; ethanol
参考文献
Giese,B.; Meister,J.
Chemische Berichte, 1977 , vol. 110, p. 2588 - 2600
反应条件
(i) CuI, (ii) /BRN= 2219715/; Multistep reaction;
参考文献
Johnson,C.R.; Dutra,G.A.
Journal of the American Chemical Society, 1973 , vol. 95, # 23 p. 7777 - 7782
反应条件
in diethyl ether
T=180°C; 0.5 h; Further byproducts given;
参考文献
Holm, Torkil
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1981 , p. 464 - 467
反应条件
T=235°C; 0.166667 h;
参考文献
Lomas,J.S.; Dubois,J.-E.
Journal of Organic Chemistry, 1974 , vol. 39, p. 1776 - 1778
反应条件
1: tBuCH2CH2Au(IPr) With xenon difluoride in chloroform-d1
0.0833333 h;
2: 3,4,5-trimethoxyphenylboronic acid in chloroform-d1
0.0833333 h;
参考文献
Tkatchouk, Ekaterina; Mankad, Neal P.; Benitez, Diego; Goddard III, William A.; Toste, F. Dean
Journal of the American Chemical Society, 2011 , vol. 133, # 36 p. 14293 - 14300
反应条件
1: iodine / CH3Cl
2: potassium tert-butylate / dimethyl sulfoxide / 3 h / 20 °C / Inert atmosphere; Darkness
View Scheme
参考文献
Oksdath-Mansilla, Gabriela; Penenory, Alicia B.
Journal of Physical Organic Chemistry, 2011 , vol. 24, # 12 p. 1136 - 1143
