1,1-二溴-2-2-二苯基环丙烷合成路线 (共 13 条)
反应条件
phenylmethyltriethylammonium bromide; sodium hydroxide in dichloromethane T=20°C; 14 h;
参考文献
Patwardhan, Neeraj N.; Gao, Ming; Carlier, Paul R.
Chemistry - A European Journal, 2011 , vol. 17, # 44 p. 12250 - 12253
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in dichloromethane 17 h; Ambient temperature; Product distribution;
参考文献
Dehmlow, Eckehard V.; Broda, Witold
Chemische Berichte, 1982 , vol. 115, # 12 p. 3894 - 3897
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in dichloromethane 17 h; Ambient temperature; Product distribution;
参考文献
Dehmlow, Eckehard V.; Broda, Witold
Chemische Berichte, 1982 , vol. 115, # 12 p. 3894 - 3897
反应条件
Li-naphthalenide in tetrahydrofuran T=-85°C; other cyclopropanes; Mechanism;
参考文献
Oku, Akira; Ose, Yasuyoshi; Kamada, Tohru; Yoshida, Tomohiro
Chemistry Letters, 1993 , # 3 p. 573 - 576
反应条件
PEG-400; potassium hydroxide; hydrogen; potassium cyanide; nickel cyanide; cobalt(II) chloride in toluene T=90 - 100°C; P=760 Torr; 96 h;
参考文献
Grushin; Alper
Tetrahedron Letters, 1991 , vol. 32, # 28 p. 3349 - 3352
反应条件
1: With ethylmagnesium bromide in tetrahydrofuran T=-60°C; 2: With acetone in tetrahydrofuran T=-60°C; 0.5 h;
参考文献
Baird, Mark S; Nizovtsev, Alexey V; Bolesov, Ivan G
Tetrahedron, 2002 , vol. 58, # 8 p. 1581 - 1593
反应条件
ethanol; phenol; cobalt(II)salen in N,N-dimethyl-formamide Electrochemical reaction;
参考文献
Yanilkin; Strunskaya; Nastapova; Maksimyuk; Bredikhina; Sharafutdinova; Bredikhin
Russian Chemical Bulletin, 2003 , vol. 52, # 4 p. 923 - 928
反应条件
hydrogenchloride; mercury dichloride; zinc in water; N,N-dimethyl-formamide T=40°C; 5 h;
参考文献
Bloodworth, A. J.; Chan, Kam Hung; Cooksey, Christopher J.
Journal of Organic Chemistry, 1986 , vol. 51, # 11 p. 2110 - 2115
反应条件
Li-naphthalenide in tetrahydrofuran T=-85°C; other cyclopropanes; Mechanism;
参考文献
Oku, Akira; Ose, Yasuyoshi; Kamada, Tohru; Yoshida, Tomohiro
Chemistry Letters, 1993 , # 3 p. 573 - 576
反应条件
1: 88 percent / n-BuLi / tetrahydrofuran; hexane / 0.75 h / -90 °C
2: 90 percent / t-BuOK / dimethylsulfoxide / 1 h / 38 °C
View Scheme
参考文献
Maercker, Adalbert; Oeffner, Kristian S.; Girreser, Ulrich
Tetrahedron, 2004 , vol. 60, # 37 p. 8245 - 8256