反应条件
1: [2-(1-methylethoxy-κO)phenylmethyl-κC](nitrato-κO,κO′){rel-(2R,5R,7S)-tricyclo[3.3.1.13,7]decane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-ylidene]}ruthenium; ethene / tetrahydrofuran / 2 h / 35 °C / 760.05 Torr / |Glovebox; |Inert atmosphere
2: [2-(1-methylethoxy-κO)phenylmethyl-κC](nitrato-κO,κO′){rel-(2R,5R,7S)-tricyclo[3.3.1.13,7]decane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-ylidene]}ruthenium / 1,2-dichloro-ethane / 24 h / 60 °C / 0.02 Torr / |Glovebox; |Inert atmosphere
View Scheme
参考文献
Marx, Vanessa M.; Herbert, Myles B.; Keitz, Benjamin K.; Grubbs, Robert H.
Journal of the American Chemical Society, 2013 , vol. 135, # 1 p. 94 - 97
