2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯合成路线 （共 6 条）
307-30-22,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇+
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
反应条件
pyridine in dichloromethane T=0 - 20°C;
参考文献
Rabai, Jozsef; Szabo, Denes; Borbas, Eszter K.; Koevesi, Istvan; Koevesdi, Istvan; Csampai, Antal; Goemoery, Agnes; Pashinnik, Valeriy E.; Shermolovich, Yuriy G.
Journal of Fluorine Chemistry, 2002 , vol. 114, # 2 p. 199 - 207
307-30-22,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇+
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
反应条件
triethylamine in dichloromethane 6 h; Ambient temperature;
参考文献
Preschera, Dietrich; Thiele, Thomas; Ruhmann, Ralf
Journal of Fluorine Chemistry, 1996 , vol. 79, # 2 p. 145 - 148
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
参考文献
Umemoto, Teruo; Gotoh, Yoshihiko
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3307 - 3314
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
反应条件
1: 1.) trifluoroacetic anhydride, 60percent aq. H2O2 / 1.) ice bath, 10 min; 2.) 0 deg C to r.t., 1 d 2: 89 percent / various solvent(s) / 24 h / 0 °C 3: 90 percent / 140 - 145 °C View Scheme
参考文献
Umemoto, Teruo; Gotoh, Yoshihiko
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 9 p. 3307 - 3314
307-30-22,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇+
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
参考文献
Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166
307-30-22,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛-1-醇+
→
17352-09-92,2,3,3,4,4,5,5,6,6,7,7,8,8,8-十五氟辛基三氟甲烷磺酸酯
参考文献
Gmelin Handbook: F: PerFHalOrg.2, 1.3.4, page 137 - 166
