(E)-A-苯乙烯二硼酸双(2,3-二甲基-2,3-丁二醇)乙酯合成路线 （共 10 条）
反应条件
Au in toluene T=100°C; 1.5 h; Green chemistry; Catalytic behavior; Reagent/catalystSolventTimeConcentration; diastereoselective reaction;
参考文献
Chen, Qiang; Zhao, Jian; Ishikawa, Yoshifumi; Asao, Naoki; Yamamoto, Yoshinori; Jin, Tienan
Organic Letters, 2013 , vol. 15, # 22 p. 5766 - 5769
反应条件
triphenylphosphine in toluene T=160°C; P=1125.11 Torr; 1.5 h; Inert atmosphere; stereoselective reaction;
参考文献
Chemistry - A European Journal, , vol. 17, # 8 p. 2467 - 2478
反应条件
1: HCl; (n-C4H9)Li / hexane; diethyl ether 2: [Pt(PPh3)4] / toluene View Scheme
参考文献
Organometallics, , vol. 21, # 21 p. 4533 - 4539
反应条件
1: HCl; (n-C4H9)Li / hexane; diethyl ether 2: [Pt(PPh3)4] / toluene View Scheme
参考文献
Organometallics, , vol. 21, # 21 p. 4533 - 4539
反应条件
[Pt(PPh3)4] in toluene (N2); addn. of phenylethynylpinacolatoborane in react. mixt. of Pt(PPh3)4 and bis(pinacolato)diborane(4) in dry toluene; stirring overnight at 80°C;
参考文献
Abu Ali, Hijazi; Al Quntar, Abed El Aziz; Goldberg, Israel; Srebnik, Morris
Organometallics, 2002 , vol. 21, # 21 p. 4533 - 4539
反应条件
1: With sodium hydroxide; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile T=25°C; 15 h; 2: With sodium hydroxide in acetonitrile
参考文献
Synthesis, , # 10 art. no. C03105SS, p. 1698 - 1700
反应条件
1: (E)-2,2'-(1-phenylethene-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) With sodium hydrogencarbonate; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile T=20°C; 15 h; 2: isopropylamine With montmorillonite K-10 in acetonitrile T=25°C; 15 h; Further stages.;
参考文献
Tetrahedron Letters, , vol. 48, # 22 p. 3841 - 3845
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium hydroxide in tetrahydrofuran; water T=70°C; Suzuki-Miyaura Coupling; 4 h;
参考文献
Alonso, Francisco; Moglie, Yanina; Pastor-Perez, Laura; Sepulveda-Escribano, Antonio
ChemCatChem, 2014 , vol. 6, # 3 p. 857 - 865
反应条件
1: With hydrogen; bis(norbornadiene)rhodium(I) tetrafluoroborate; (S,R)-Walphos (SL-W001-1) P=11400.8 Torr; 2: With dihydrogen peroxide Product distribution / selectivity;
参考文献
UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL
Patent: WO2005/12209 A2, 2005 ;
Location in patent: Page/Page column 61 ;
反应条件
1: With sodium hydroxide; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate) in acetonitrile T=25°C; 15 h; 2: With sodium hydroxide in acetonitrile
参考文献
Synthesis, , # 10 art. no. C03105SS, p. 1698 - 1700
