(S)-(+)-5-己烯-2-醇合成路线 (共 51 条)
反应条件
1: (4-hydroxy-pentyl)-triphenyl-phosphonium; iodide With 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile Heating; 2: formaldehyd in acetonitrile
参考文献
Bulletin of the Chemical Society of Japan, , vol. 78, # 12 p. 2209 - 2213
反应条件
pyridin-2-yl hydrobromide in pyridine
参考文献
Journal of Heterocyclic Chemistry, , vol. 16, p. 39 - 45
反应条件
pyridin-2-yl hydrobromide in pyridine
参考文献
Journal of Heterocyclic Chemistry, , vol. 16, p. 39 - 45
反应条件
sodium hydroxide; water
参考文献
Organic Letters, , vol. 10, # 13 p. 2789 - 2792
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
参考文献
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, , vol. 270, p. 1305 - 1307
反应条件
in tetrahydrofuran T=-50 - 20°C; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 15, # 42 p. 11078 - 11082
反应条件
hydrogenchloride; water in methanol; toluene 1 h; RefluxInert atmosphere;
参考文献
Arrowsmith, Merle; Hadlington, Terrance J.; Hill, Michael S.; Kociok-Koehn, Gabriele
Chemical Communications, 2012 , vol. 48, # 38 p. 4567 - 4569
反应条件
2,2'-azo-bisisobutyronitrile in benzene T=40°C; Irradiationdifferent concentrations of Bu3SnH, without irradiation, absence of azobis(isobutyronitrile), presence of p-dinitrobenzene, presence of oxygen; Product distributionMechanism;
参考文献
Bowman, W. Russell; Crosby, David; Westlake, Paul J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 1 p. 73 - 80
反应条件
in tetrahydrofuran from -78 deg C to RT; Yields of byproduct given;
参考文献
Tanaka, Tetsuaki; Inoue, Tetsuya; Kamei, Katsuhide; Murakami, Kazuo; Iwata, Chuzo
Journal of the Chemical Society, Chemical Communications, 1990 , # 13 p. 906 - 908
反应条件
C51H41ClN3O2P2Ru(1+)*F6P(1-); potassium tert-butylate; triphenylphosphine; isopropyl alcohol T=80°C; 24 h; Inert atmosphereSealed tube; Reagent/catalyst; chemoselective reaction;
参考文献
Moore, Cameron M.; Szymczak, Nathaniel K.
Chemical Communications, 2013 , vol. 49, # 4 p. 400 - 402