1,1-二乙氧基-3-甲基-2-丁烯合成路线 （共 26 条）
参考文献
Fischer; Ertel; Loewenberg
Chemische Berichte, 1931 , vol. 64, p. 32
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Fischer; Loewenberg
Justus Liebigs Annalen der Chemie, 1932 , vol. 494, p. 283
Chemische Berichte, 1933 , vol. 66, p. 670
反应条件
silica gel in dichloromethane; water 0.7 h; Ambient temperature;
参考文献
Journal of Chemical Research, Miniprint, , # 9 p. 2552 - 2578
参考文献
Chemische Berichte, , vol. 64, p. 32
Justus Liebigs Annalen der Chemie, , vol. 494, p. 283
Chemische Berichte, , vol. 66, p. 670
反应条件
3-Methylpyridine in xylene T=115°C; 24 h;
参考文献
North, Jeffrey T.; Kronenthal, David R.; Pullockaran, Annie J.; Real, Sharon D.; Chen, Helen Y.
Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3397 - 3400
反应条件
1: 50 percent / pyridinium tosylate / benzene / 24 h / Heating 2: 81 percent / diethylzinc / 1,2-dichloro-ethane; hexane / 24 h / 0 °C 3: 79 percent / O3 / ethyl acetate / 1 h / 23 °C 4: 2 N aq. NaOH / ethanol / 1 h / Ambient temperature View Scheme
参考文献
Kang, Jahyo; Lim, Geun Jho; Yoon, Suk Kyoon; Kim, Moohi Yoo
Journal of Organic Chemistry, 1995 , vol. 60, # 3 p. 564 - 577
反应条件
3-Methylpyridine in xylene T=118°C; 24 h;
参考文献
North, Jeffrey T.; Kronenthal, David R.; Pullockaran, Annie J.; Real, Sharon D.; Chen, Helen Y.
Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3397 - 3400
反应条件
potassium carbonate in ethanol; para-xylene
反应条件
potassium hydrogensulfate in ethanol
1 h;
参考文献
North, Jeffrey T.; Kronenthal, David R.; Pullockaran, Annie J.; Real, Sharon D.; Chen, Helen Y.
Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3397 - 3400
参考文献
SmithKline Beecham p.l.c.
Patent: US5919953 A1, 1999 ;
反应条件
potassium carbonate in ethanol
参考文献
BASF Aktiengesellschaft
Patent: US6313322 B1, 2001 ;
