7-十四碳炔-6,9-二醇合成路线 （共 5 条）
反应条件
1: With tert.-butylhydroperoxide; selenium(IV) oxide T=20°C; Sharpless reaction; 24 h; 2: With sodium tetrahydroborate in methanol T=0°C;
参考文献
Synlett, , # 1 p. 120 - 122
反应条件
1.1: BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C 1.2: 94 percent / tetrahydrofuran; hexane / 0.58 h / 0 - 20 °C 2.1: t-BuOOH; SeO2 / 24 h / 20 °C 2.2: NaBH4 / methanol / 0.25 h View Scheme
参考文献
Synthesis, , # 1 p. 128 - 134
反应条件
1.1: BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C 1.2: 94 percent / tetrahydrofuran; hexane / 0.58 h / 0 - 20 °C 2.1: t-BuOOH; SeO2 / 24 h / 20 °C 2.2: NaBH4 / methanol / 0.25 h View Scheme
参考文献
Synthesis, , # 1 p. 128 - 134
反应条件
[Rh(rac-BINAP)]BF4 in 1,2-dichloro-ethane T=80°C; 1 h;
参考文献
Tanaka, Ken; Shoji, Takeaki; Hirano, Masao
European Journal of Organic Chemistry, 2007 , # 16 p. 2687 - 2699
反应条件
1: 73 percent / [Rh(rac-BINAP)]BF4 / 1,2-dichloro-ethane / 1 h / 80 °C
2: 7 percent / [Rh(rac-BINAP9]BF4 / 1,2-dichloro-ethane / 20 h / 80 °C
View Scheme
参考文献
Tanaka, Ken; Shoji, Takeaki; Hirano, Masao
European Journal of Organic Chemistry, 2007 , # 16 p. 2687 - 2699
