1: cis-2-hexene-1-ol With [Rh(acac)2(CO)2]; C17H20NOP; toluene-4-sulfonic acid in benzene T=55°C; 0.166667 h; Inert atmosphere; 2: carbon monoxide With hydrogen in benzene T=55°C; P=2585.81 Torr; 16 h; 3: With sodium chlorite; sodium dihydrogenphosphate; dihydrogen peroxide in water; acetonitrile T=10 - 20°C; Pinnick oxidation; 3 h; Inert atmosphere; regioselective reaction;

1: 1-Hydroxy-2-trans-hexene With [Rh(acac)2(CO)2]; C17H20NOP; toluene-4-sulfonic acid in benzene T=55°C; 0.166667 h; Inert atmosphere; 2: carbon monoxide With hydrogen in benzene T=55°C; P=2585.81 Torr; 16 h; 3: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene in water; tert-butyl alcohol Pinnick oxidation; 6 h; Inert atmosphere; regioselective reaction;

hydrogen; palladium on activated charcoal in ethyl acetate P=760.051 Torr;

hydrogenchloride; oxygen; copper dichloride; palladium dichloride in tetrahydrofuran P=760 Torr; Ambient temperature;

1: cis-3-hexene-1-ol 0.5 h; Inert atmosphereMolecular sieve; 2: carbon monoxide With dicarbonylacetylacetonato rhodium (I); Ph2P(OMe); hydrogen; lithium chloride in toluene T=40°C; P=15001.5 Torr; 20 h; Molecular sieve; 3: With aluminum oxide; sodium acetate; pyridinium chlorochromate in dichloromethane T=20°C; 12 h; regioselective reaction;

1: trans-3-hexene-1-ol 0.5 h; Inert atmosphereMolecular sieve; 2: carbon monoxide With dicarbonylacetylacetonato rhodium (I); Ph2P(OMe); hydrogen; lithium chloride in toluene T=40°C; P=15001.5 Torr; 20 h; Molecular sieve; 3: With aluminum oxide; sodium acetate; pyridinium chlorochromate in dichloromethane T=20°C; 12 h; regioselective reaction;

hydrogenchloride; oxygen; copper dichloride; palladium dichloride in tetrahydrofuran P=760 Torr; Ambient temperature;

titanium(IV) isopropylate; hydrogenchloride; isopropylmagnesium chloride 1.) ether, from -45 to -40 deg C, 1 h, 2.) RT, 30 min; Yield given. Multistep reaction;

titanium(IV) isopropylate; hydrogenchloride; isopropylmagnesium chloride 1.) ether, from -45 to -40 deg C, 1 h, 2.) RT, 30 min; Yield given. Multistep reaction;

1: DCC 2: 55 percent / ethanol / Irradiation View Scheme