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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
17475-41-1
合成路线
(共 35 条)
74532-85-7
(R)-1-(2-溴苯基)丙烷-1-醇
→
反应条件
17475-41-1
反应条件
in N,N-dimethyl-formamide 12 h; Inert atmosphereReflux;
参考文献
COUNCIL OF SCIENTIFIC and INDUSTRIAL RESEARCH; REDDY, Santhosh, Rekula; PRAGATI, Kishore, Prasad; NAGA, Kiran, Chaithanya, Indukuru; SUDALAI, Arumugam
Patent: WO2013/102935 A2, 2013 ;
Location in patent: Page/Page column 20 ;
123-38-6
丙醛
+
693232-15-4
→
反应条件
17475-41-1
反应条件
1: 2-(methoxycarbonyl)phenylzinc iodide With Chromium (III) chloride in various solvent(s) T=20°C; Metallation; 6 h; 2: propionaldehyde in various solvent(s) T=20°C; Addition; Further stages.;
参考文献
Ogawa, Yoshihiro; Saiga, Akihiro; Mori, Mitsuo; Shibata, Takanori; Takagi, Kentaro
Journal of Organic Chemistry, 2000 , vol. 65, # 4 p. 1031 - 1036
2438-03-1
2-丙基苯甲酸
→
反应条件
17475-41-1
反应条件
Sodium bromate; sodium hydrogensulfite in water; ethyl acetate T=20°C; 40 h;
参考文献
Bayer, Ernst; Hayat, Safdar; Atta-Ur-Rahman; Choudhary, M. Iqbal; Khan, Khalid Mohammed; Shah, Syed Tasadaque Ali; Imran-Ul-Haq; Anwar, M. Usman; Voelter, Wolfgang
Arzneimittel-Forschung/Drug Research, 2005 , vol. 55, # 10 p. 588 - 597
3158-74-5
2-环丙基苯甲酸
→
反应条件
17475-41-1
反应条件
sulfuric acid T=-15 - -5°C; Rearrangement; 1 h;
参考文献
Mochalov; Fedotov; Kutateladze; Trofimova; Shabarov; Zefirov
Chemistry of Heterocyclic Compounds, 1998 , vol. 34, # 3 p. 288 - 293
91587-24-5
→
反应条件
87-41-2
苯酞
+
17475-41-1
+
136391-68-9
反应条件
T=450°C; P=1E-05 Torr;
参考文献
Tomioka, Hideo; Kobayashi, Noriyuki; Murata, Shigeru; Ohtawa, Yasuki
Journal of the American Chemical Society, 1991 , vol. 113, # 23 p. 8771 - 8778
136391-65-6
→
反应条件
87-41-2
苯酞
+
17475-41-1
+
136391-68-9
反应条件
T=450°C; P=1E-05 Torr;
参考文献
Tomioka, Hideo; Kobayashi, Noriyuki; Murata, Shigeru; Ohtawa, Yasuki
Journal of the American Chemical Society, 1991 , vol. 113, # 23 p. 8771 - 8778
→
反应条件
17475-41-1
反应条件
(Sp,S)-Ph-CH(Me)-N=C(Me)-[2,2]paracyclophane in tetrahydrofuran; toluene T=0°C; 40 h;
参考文献
Knepper, Kerstin; Ziegert, Robert E.; Braese, Stefan
Tetrahedron, 2004 , vol. 60, # 39 p. 8591 - 8603
207673-23-2
→
反应条件
17475-41-1
反应条件
in dimethyl sulfoxide 72 h; Inert atmosphereUV-irradiation;
参考文献
Gerbino, Dario C.; Augner, Daniel; Slavov, Nikolay; Schmalz, Hans-Guenther
Organic Letters, 2012 , vol. 14, # 9 p. 2338 - 2341
→
反应条件
17475-41-1
+
16824-02-5
3-乙氧基-1(3H)-异苯并呋喃酮
反应条件
2-(dimethylamino)-ethanol in tetrahydrofuran; toluene T=0°C; 40 h;
参考文献
Knepper, Kerstin; Ziegert, Robert E.; Braese, Stefan
Tetrahedron, 2004 , vol. 60, # 39 p. 8591 - 8603
61436-73-5
→
反应条件
29539-21-7
3-甲基异色烯-1-酮
+
17475-41-1
+
83285-42-1
反应条件
palladium diacetate; copper diacetate; water; potassium hydrogencarbonate in N,N-dimethyl-formamide T=100°C; 2.5 h; Yield given. Yields of byproduct given;
参考文献
Roshchin, Alexander I.; Kel'chevski, Sergey M.; Bumagin, Nikolai A.
Journal of Organometallic Chemistry, 1998 , vol. 560, # 1-2 p. 163 - 167
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