三(三甲基硅基氧化)硅醇合成路线 （共 12 条）
反应条件
1: bis-trimethylsilyl ether With sulfuric acid T=0 - 10°C; 0.5 h; 2: ethyl orthosilicate T=10°C; 1.75 h; 3: With water T=5 - 50°C; 4 h;
参考文献
Kanebo Cosmetics, Inc.; Shin-Etsu Chemical Co., Ltd.
Patent: EP1607081 A1, 2005 ;
Location in patent: Page/Page column 14-16 ;
反应条件
1: ethanol; bis-trimethylsilyl ether T=0 - 10°C; 2: With trifluorormethanesulfonic acid T=10°C; 0.5 h; 3: ethyl orthosilicate With water more than 3 stages;
参考文献
Kanebo Cosmetics, Inc.; Shin-Etsu Chemical Co., Ltd.
Patent: EP1607081 A1, 2005 ;
Location in patent: Page/Page column 14-16 ;
反应条件
1: methanol; bis-trimethylsilyl ether T=0 - 10°C; 2: With sulfuric acid T=10°C; 0.5 h; 3: orthosilicic acid tetramethyl ester With water more than 3 stages;
参考文献
Kanebo Cosmetics, Inc.; Shin-Etsu Chemical Co., Ltd.
Patent: EP1607081 A1, 2005 ;
Location in patent: Page/Page column 14-17 ;
反应条件
1: bis-trimethylsilyl ether With methanol; sulfuric acid T=5 - 10°C; 1 h; 2: orthosilicic acid tetramethyl ester T=5 - 10°C; 1.5 h; 3: With sulfuric acid; water more than 3 stages;
参考文献
Shin-Etsu Chemical Co., Ltd.
Patent: EP1510520 A1, 2005 ;
Location in patent: Page/Page column 13-14 ;
反应条件
sodium hydroxide in water 1 h;
参考文献
Scheim, U.; Grosse-Ruyken, H.; Ruehlmann, K.; Porzel, A.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 27 - 32
反应条件
sodium hydroxide in diethyl ether
参考文献
Kownacki, Ireneusz; Marciniec, Bogdan; Szubert, Karol; Kubicki, Maciej; Jankowska, Magdalena; Steinberger, Helmut; Rubinsztajn, Slawomir
Applied Catalysis A: General, 2010 , vol. 380, # 1-2 p. 105 - 112
反应条件
1: 83 percent / bromine / CCl4 / 0.5 h 2: 83 percent / NaOH / H2O / 1 h View Scheme
参考文献
Mueller et al.
Journal fuer Praktische Chemie (Leipzig), 1959 , vol. <4>9, p. 63,67,70
反应条件
1: 75 percent / trichlorosilane, conc. H2SO4 / H2O / 0.5 h / 50 °C 2: 83 percent / bromine / CCl4 / 0.5 h 3: 83 percent / NaOH / H2O / 1 h View Scheme
参考文献
Scheim, U.; Grosse-Ruyken, H.; Ruehlmann, K.; Porzel, A.
Journal of Organometallic Chemistry, 1986 , vol. 312, p. 27 - 32
反应条件
bis-trimethylsilyl ether; olivine; water in butanone 1.) 5 min; 2.) 1 h;
参考文献
Kuroda, Kazuyuki; Koike, Tetsuhiro; Kato, Chuzo
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981 , p. 1957 - 1960
反应条件
[P(cyclohexyl)3]2(CO)(Cl)Ru(H) in toluene T=120°C; 24 h;
参考文献
Marciniec, Bogdan; Pawluc, Piotr; Hreczycho, Grzegorz; Macina, Anna; Madalska, Martyna
Tetrahedron Letters, 2008 , vol. 49, # 8 p. 1310 - 1313
