(S)-(-)-N-苄基-1-苯基-乙胺合成路线 （共 37 条）
反应条件
1: molecular sieves 4 Angstroem / toluene / Heating 2: H2; [Ir(1,5-cyclooctadiene)Cl]2; (R)-tert-butylphosphinoylbenzene / pyridine / toluene / 120 h / 0 °C / 18751.5 Torr View Scheme
参考文献
Organic Letters, , vol. 5, # 9 p. 1503 - 1506
反应条件
1: molecular sieves 4 Angstroem / toluene / Heating 2: H2; [Ir(1,5-cyclooctadiene)Cl]2; (R)-tert-butylphosphinoylbenzene / pyridine / toluene / 120 h / 0 °C / 18751.5 Torr View Scheme
参考文献
Organic Letters, , vol. 5, # 9 p. 1503 - 1506
反应条件
lithium aluminium tetrahydride in tetrahydrofuran Heating;
参考文献
Journal of the American Chemical Society, , vol. 126, # 13 p. 4343 - 4354
反应条件
1: Et3N / CH2Cl2 / 0.5 h 2: LiAlH4 / tetrahydrofuran / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 126, # 13 p. 4343 - 4354
反应条件
1: 83 percent / benzene / Heating 2: 90 percent / sodium borohydride View Scheme
参考文献
Journal of the American Chemical Society, , vol. 109, # 11 p. 3370 - 3377
反应条件
3,3'-bis(9-anthryl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate; diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate in toluene T=57°C; P=125.263 Torr; 120 h; Inert atmosphereDean-Stark trap; optical yield given as percent eeenantioselective reaction;
参考文献
Synlett, , # 18 p. 2708 - 2710
反应条件
N,N'-dimethyl-N,N'-propyleneurea; sodium carbonate Heating;
参考文献
Huelgas, Gabriela; Bernes, Sylvain; Sanchez, Mario; Quintero, Leticia; Juaristi, Eusebio; Anaya de Parrodi, Cecilia; Walsh, Patrick J.
Tetrahedron, 2007 , vol. 63, # 51 p. 12655 - 12664
反应条件
sodium tetrahydroborate in methanol; toluene T=20°C; 3 h;
参考文献
Synthetic Communications, , vol. 36, # 19 p. 2859 - 2875
反应条件
1: toluene / 24 h / 20 °C / |Inert atmosphere; |Molecular sieve 2: benzo[1,3,2]dioxaborole; 1,1,1-trifluoro-N-(4-oxido-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide / pentane / 24 h / -78 - -22 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Tetrahedron Letters, , vol. 54, # 6 p. 470 - 473
反应条件
1: toluene / 24 h / 20 °C / |Inert atmosphere; |Molecular sieve 2: benzo[1,3,2]dioxaborole; 1,1,1-trifluoro-N-(4-oxido-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide / pentane / 24 h / -78 - -22 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Tetrahedron Letters, , vol. 54, # 6 p. 470 - 473
