1H,1H,2H,2H-全氟辛醇丙烯酸酯合成路线 （共 5 条）
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
→
反应条件
sulfuric acid; hydroquinone in benzene Heating;
参考文献
Journal of Fluorine Chemistry, , vol. 38, p. 47 - 74
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
→
反应条件
2,6-di-tert-butyl-4-methyl-phenol; triethylamine in diethyl ether T=20°C; 16 h;
参考文献
Hazendonk, Paul; Harris, Robin K.; Galli, Giancarlo; Pizzanelli, Silvia
Physical Chemistry Chemical Physics, 2002 , vol. 4, # 3 p. 507 - 513
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9-10 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 6-7; 8-9 ;
