1,3-反式二甲基环戊烷合成路线 （共 20 条）
反应条件
hydrogen; oxalic acid; platinum(IV) oxide 1.) 130 - 160 deg C, 2.) acetic acid; Multistep reaction;
参考文献
Beckwith, Athelstan L. J.; Easton, Christopher J.; Lawrence, Tony; Serelis, Algirdas K.
Australian Journal of Chemistry, 1983 , vol. 36, # 3 p. 545 - 556
反应条件
tri-n-butyl-tin hydride in benzene T=80°C; Title compound not separated from byproducts;
参考文献
Beckwith, Athelstan L. J.; Lawrence, Tony; Serelis, Algirdas K.
Journal of the Chemical Society, Chemical Communications, 1980 , # 11 p. 484 - 485
反应条件
tri-n-butyl-tin hydride in benzene T=80°C; Title compound not separated from byproducts;
参考文献
Beckwith, Athelstan L. J.; Lawrence, Tony; Serelis, Algirdas K.
Journal of the Chemical Society, Chemical Communications, 1980 , # 11 p. 484 - 485
反应条件
1: HgSO4; H2SO4; methanol / anschl. mit wss. H3PO4 2: Raney nickel; ethanol / 85 °C / 73550.8 Torr / Hydrogenation 3: oxalic acid / 140 °C 4: palladium/charcoal / Hydrogenation View Scheme
参考文献
Koperina et al.
Zhurnal Obshchei Khimii, 1950 , vol. 20, p. 1498,1500
Chem.Abstr., 1951 , p. 2417
反应条件
1: Raney nickel; ethanol / 85 °C / 73550.8 Torr / Hydrogenation 2: oxalic acid / 140 °C 3: palladium/charcoal / Hydrogenation View Scheme
参考文献
Koperina et al.
Zhurnal Obshchei Khimii, 1950 , vol. 20, p. 1498,1500
Chem.Abstr., 1951 , p. 2417
反应条件
1: oxalic acid / 140 °C 2: palladium/charcoal / Hydrogenation View Scheme
参考文献
Koperina et al.
Zhurnal Obshchei Khimii, 1950 , vol. 20, p. 1498,1500
Chem.Abstr., 1951 , p. 2417
反应条件
palladium on activated charcoal Hydrogenation;
参考文献
Koperina et al.
Zhurnal Obshchei Khimii, 1950 , vol. 20, p. 1498,1500
Chem.Abstr., 1951 , p. 2417
反应条件
methanol; N,N,N',N'',N''-pentamethyldiethylenetriamine 1.) n-pentane, diethyl ether, a) -78 deg C, 5 min, b) RT, 1 h; other substituted 5-hexen-1-yllithiums; other Lewis bases; Product distribution;
参考文献
Bailey, William F.; Khanolkar, Atmaram D.; Gavaskar, Kaustubh; Ovaska, Timo V.; Rossi, Kyllikki; Thiel, Yvonne; Wiberg, Kenneth B.
Journal of the American Chemical Society, 1991 , vol. 113, # 15 p. 5720 - 5727
反应条件
diethyl ether katalytische Dehydratisierung des Reaktionsprodukts und anschliessende Hydrierung an Nickel unter Druck;
参考文献
Boord et al.
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 615
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene T=45°C; var. temp., other bromoalkenes; MechanismProduct distribution;
参考文献
Beckwith, Athelstan L. J.; Easton, Christopher J.; Lawrence, Tony; Serelis, Algirdas K.
Australian Journal of Chemistry, 1983 , vol. 36, # 3 p. 545 - 556
