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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
17595-92-5
合成路线
（共 12 条）
1003-09-4
2-溴噻吩
+
16750-63-3
2-甲氧基苯基溴化镁
→
反应条件
17595-92-5
反应条件
PEPPSI™-IPr catalyst in tetrahydrofuran; ethylene glycol dimethyl ether T=60°C; Kumada-Tamao-Corriu reaction; 24 h;
参考文献
Total Synthesis, Ltd.
Patent: US2007/73055 A1, 2007 ;
Location in patent: Page/Page column 13-14; 22 ;
578-57-4
2-溴苯甲醚
+
5713-61-1
苯硫基溴化镁
→
反应条件
17595-92-5
反应条件
lithium chloride; PEPPSI™-IPr catalyst in tetrahydrofuran; ethylene glycol dimethyl ether T=20°C; Kumada-Tamao-Corriu reaction; 24 h;
参考文献
Total Synthesis, Ltd.
Patent: US2007/73055 A1, 2007 ;
Location in patent: Page/Page column 13-14; 22 ;
188290-36-0
+
529-28-2
2-碘苯甲醚
→
反应条件
17595-92-5
反应条件
n-butyllithium; zinc(II) chloride; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran; hexane T=20°C; 2.5 h;
参考文献
Ohri, Rachana V.; Radosevich, Alexander T.; Hrovat, K. James; Musich, Christine; Huang, David; Holman, Theodore R.; Toste, F. Dean
Organic Letters, 2005 , vol. 7, # 12 p. 2501 - 2504
96-43-5
2-氯噻吩
+
5720-06-9
2-甲氧基苯基硼酸
→
反应条件
17595-92-5
反应条件
potassium phosphate; N,N'-bis-[2,4,6-tri(3,3,3-trifluoropropyl)phenyl]-4,5-dihydroimidazolium chloride; palladium diacetate in tetrahydrofuran; water Suzuki-Miyaura cross-coupling; 12 h; Inert atmosphereReflux;
参考文献
Liu, Taoping; Zhao, Xiaoming; Shen, Qilong; Lu, Long
Tetrahedron, 2012 , vol. 68, # 32 p. 6535 - 6547
1003-09-4
2-溴噻吩
+
100-66-3
苯甲醚
→
反应条件
17595-92-5
反应条件
1: methoxybenzene With N,N,N',N,-tetramethylethylenediamine; sec.-butyllithium in tetrahydrofuran; cyclohexane T=-78°C; 2 h; 2: With indium(III) chloride in tetrahydrofuran; cyclohexane T=-78 - 20°C; 3: thien-2-yl bromide With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran; cyclohexane Heating;
参考文献
Pena, Miguel A.; Sestelo, Jose Perez; Sarandeses, Luis A.
Journal of Organic Chemistry, 2007 , vol. 72, # 4 p. 1271 - 1275
5713-61-1
苯硫基溴化镁
+
16750-63-3
2-甲氧基苯基溴化镁
→
反应条件
17595-92-5
+
4877-93-4
2,2’-二甲氧基联苯
+
492-97-7
2,2'-联二噻吩
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere; chemoselective reaction;
参考文献
Cahiez, Gerard; Duplais, Christophe; Buendia, Julien
Angewandte Chemie, International Edition, 2009 , vol. 48, # 36 p. 6731 - 6734
→
反应条件
17595-92-5
反应条件
palladium diacetate in ethylene glycol dimethyl ether T=60°C; 0.5 h;
参考文献
Xia, Min; Chen, Zhen-Chu
Synthetic Communications, 1999 , vol. 29, # 14 p. 2457 - 2465
766-51-8
2-氯苯甲醚
+
45438-80-0
2-噻吩基溴化锌
→
反应条件
17595-92-5
反应条件
tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in tetrahydrofuran T=65°C; Negishi cross-coupling; 24 h; Inert atmosphere;
参考文献
Luzung, Michael R.; Patel, Jigar S.; Yin, Jingjun
Journal of Organic Chemistry, 2010 , vol. 75, # 23 p. 8330 - 8332
188290-36-0
+
5720-06-9
2-甲氧基苯基硼酸
→
反应条件
17595-92-5
反应条件
manganese triacetate Heating;
参考文献
Demir, Ayhan S.; Reis, Oemer; Emrullahoglu, Mustafa
Journal of Organic Chemistry, 2003 , vol. 68, # 2 p. 578 - 580
578-57-4
2-溴苯甲醚
+
5713-61-1
苯硫基溴化镁
→
反应条件
17595-92-5
+
492-97-7
2,2'-联二噻吩
反应条件
triphenylphosphine; Pd bipyridyl anchored nanosized mesoporous silica MCM-41 in tetrahydrofuran Kumada-Corriu reaction; 24 h; Heating;
参考文献
Tsai, Fu-Yu; Lin, Bo-Nan; Chen, Ming-Jie; Mou, Chung-Yuan; Liu, Shiuh-Tzung
Tetrahedron, 2007 , vol. 63, # 20 p. 4304 - 4309
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