5 5'-二甲基-2,2'-二吡啶合成路线 （共 36 条）
反应条件
1: KMnO4 / H2O / Heating 2: 64 percent / conc. H2SO4 / 16 h / Heating View Scheme
参考文献
Elliott, C. Michael; Hershenhart, Elise J.
Journal of the American Chemical Society, 1982 , vol. 104, # 26 p. 7519 - 7526
反应条件
in acetone inert atmosphere, Schlenk techniques; slurry (V- and Na-compds., bpy and solvent) stirring overnight at room temp., NaCl ppt. filtration off, NBu4ClO4 addn. to filtrate, solvent removal (vac.), residue washing (Et2O), redissoln. (acetone); distn. (A4 molecular sieve), pptn. on large excess Et2O addn., ppt. filtration off, washing (Et2O), vac. drying; elem. anal.;
参考文献
Castro, Stephanie L.; Sun, Ziming; Grant, Craig M.; Bollinger, John C.; Hendrickson, David N.; Christou, George
Journal of the American Chemical Society, 1998 , vol. 120, # 10 p. 2365 - 2375
反应条件
N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile in tetrachloromethane
T=77°C; 17 h;
参考文献
Ipe, Binil Itty; Yoosaf, Karuvath; Thomas, Kakkudiyil George
Journal of the American Chemical Society, 2006 , vol. 128, # 6 p. 1907 - 1913
反应条件
N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile in tetrachloromethane
T=77°C; 17 h; Inert atmosphereSchlenk techniqueGlovebox;
参考文献
Goforth, Sarah K.; Walroth, Richard C.; McElwee-White, Lisa
Inorganic Chemistry, 2013 , vol. 52, # 10 p. 5692 - 5701
反应条件
1: oxidation
3: ammonia
View Scheme
参考文献
Baxter, Paul N.W.; Connor, Joseph A.
Journal of Organometallic Chemistry, 1988 , vol. 355, p. 193 - 196
反应条件
1: 22 percent / NBS; VAZO / CCl4 / 1 h / Heating
2: 90 percent / NaN3 / dimethylformamide / 17 h / 90 °C
View Scheme
参考文献
Xing, Bengang; Yu, Chun-Wing; Ho, Pak-Leung; Chow, Kin-Hung; Cheung, Terence; Gu, Hongwei; Cai, Zongwei; Xu, Bing
Journal of Medicinal Chemistry, 2003 , vol. 46, # 23 p. 4904 - 4909
