bis-(diphenylphosphino)-ethane; CO in dichloromethane under N2, soln. of ((Ph2PCH2)2)Cu2Cl2 was prepd. by addn. of CuCl and (Ph2PCH2)2 to CH2Cl2, Na2Fe2(CO)8 was prepd. from equimolar amts. of Fe(CO)5 and Na2Fe(CO)4 and added in small increments over 45 min, stirred under CO for 16 h; filtered, concd., pptd. by pentane addn.; isolation of Fe3(CO)12 on evapn. of filtrate;
参考文献
Journal of the American Chemical Society, , vol. 107, # 26 p. 7914 - 7920
in hexane to suspn. Fe2(CO)9 in n-hexane soln. ligand in n-hexane was added quickly at -50°C without stirring, suspn. was warmed to room temp., stirred for 5 h; soln. was filtered, concd. and cooled to 5°C for 10 h, soln. was filtered and concd.;
参考文献
Kuprat, Marcus; Lehmann, Mathias; Schulz, Axel; Villinger, Alexander
Inorganic Chemistry, 2011 , vol. 50, # 12 p. 5784 - 5792
in hexane Irradiation (UV/VIS); a soln. of Os-complex and Fe-complex in hexane was irradiated with 366 nm light for 2 h under N2; monitored by IR, evapd., chromd. (SiO2, hexane, hexane/benzene), evapd.;
参考文献
Burkhardt, Eric W.; Geoffroy, Gregory L.
Journal of Organometallic Chemistry, 1980 , vol. 198, # 2 p. 179 - 188
