in tetrahydrofuran (N2); std. Schlenk technique; soln. of Fe complex in THF was treated with ligand; stirred under reflux for 30 min; evapd. (vac.); chromd. (silica, CH2Cl2/hexane, 1/1); elem. anal.;
in tetrahydrofuran; methanol N2-atmosphere; mixing Fe3(CO)12 with excess carbide, THF addn., stirring(room temp., 12 h), distn. off of Fe(CO)5 (high vac.), dissoln., addn. of satd. Et4NBr (in MeOH);
参考文献
Manning, Mark C.; Trogler, William C.
Inorganica Chimica Acta, 1981 , vol. 50, p. 247 - 250
