2-甲基-2-金刚烷基甲基丙烯酸酯合成路线 （共 11 条）
反应条件
methylmagnesium bromide; sodium hydrogencarbonate in tetrahydrofuran; hexane
参考文献
Fujitsu Limited
Patent: US6248920 B1, 2001 ;
反应条件
triethylamine in isobutyl methylketone T=80°C; 24 h;
参考文献
Sumitomo Chemical Company, Limited
Patent: US6344582 B1, 2002 ;
Location in patent: Example 4 ;
反应条件
sodium hydroxide; p-toluenesulfonic acid monohydrate in toluene
参考文献
TOSOH CORPORATION
Patent: US2003/139613 A1, 2003 ;
反应条件
1: adamantane monoketone (adamantanone); methylmagnesium bromide in tetrahydrofuran T=20°C; 3 h; 2: 2-methyl-acryloyl chloride With pyridine in tetrahydrofuran T=50°C; 3 h;
参考文献
US2004/15008 A1, ;
Page 5-6 ;
反应条件
1: adamantane monoketone (adamantanone); methylmagnesium bromide in tetrahydrofuran; diethyl ether T=-25 - -10°C; 1 h; 2: methacrylic acid anhydride With triethylamine in tetrahydrofuran; diethyl ether T=25°C; 1.5 h;
参考文献
MITSUBISHI GAS CHEMICAL COMPANY, INC.
Patent: EP1215193 A2, 2002 ;
Location in patent: Example 6 ;
反应条件
1: adamantane monoketone (adamantanone); methyllithium in tetrahydrofuran; diethyl ether T=-25 - -20°C; 1 h; 2: methacrylic acid anhydride With triethylamine in tetrahydrofuran; diethyl ether T=25°C; 1.5 h;
参考文献
MITSUBISHI GAS CHEMICAL COMPANY, INC.
Patent: EP1215193 A2, 2002 ;
Location in patent: Example 5 ;
反应条件
pyridine in tetrahydrofuran; hexane
参考文献
Murata, Naoshi; Tamura, Kimio; Yoshida, Yasukazu; Ohkita, Motomu
Patent: US2003/181763 A1, 2003 ;
反应条件
1: adamantane monoketone (adamantanone); methyllithium in tetrahydrofuran; diethyl ether T=-25 - -20°C; 1 h; 2: methacrylic acid methyl ester in tetrahydrofuran; diethyl ether T=55°C; 4.5 h;
参考文献
MITSUBISHI GAS CHEMICAL COMPANY, INC.
Patent: EP1215193 A2, 2002 ;
Location in patent: Example 1 ;
