乙基3-(三甲基硅基)丙酸酯合成路线 （共 12 条）
反应条件
acetic anhydride in not given
参考文献
Sommer, L. H.; Marans, N. S.
Journal of the American Chemical Society, 1950 , vol. 72, p. 1935 - 1939
反应条件
sodium in ethanol Substitution; 36 h; Heating;
参考文献
Tilley, Leon J.; Shiner Jr.
Journal of Physical Organic Chemistry, 1999 , vol. 12, # 7 p. 564 - 576
参考文献
Sommer, L. H.; Marans, N. S.
Journal of the American Chemical Society, 1950 , vol. 72, p. 1935 - 1939
反应条件
bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=90°C; P=44130.5 Torr; 16 h; other temperatures, other solvents, other Pd-, Pt- and/or Co-catalysts, other vinylsilanes; α- or β-regioselectivity/regiospecifity of hydroesterification; Product distributionMechanism;
参考文献
Takeuchi; Ishii; Sato
Journal of the Chemical Society - Series Chemical Communications, 1991 , # 18 p. 1247 - 1248
反应条件
lithium 1) ice-bath, THF, 45 min; 2) THF, 7 - 8 deg C (5 h), room temperature (40 h); Yield given. Multistep reaction;
参考文献
Trost,B.M.; Chan,D.M.
Journal of the American Chemical Society, 1983 , vol. 105, p. 2326
反应条件
bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=90°C; P=44130.5 Torr; other vinylsilanes; other catalyst; var. solvents, temp. and pressure; Product distribution;
参考文献
Takeuchi, Ryo; Ishii, Naomi; Sugiura, Masaharu; Sato, Nobuhiro
Journal of Organic Chemistry, 1992 , vol. 57, # 15 p. 4189 - 4194
反应条件
di-tert-butyl peroxide T=140°C;
参考文献
Makaeva, R. M.; Musavirov, R. S.; Kantor, E. A.; Terentev, A. B.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1985 , vol. 34, p. 1889 - 1892
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1985 , # 9 p. 2047 - 2050
反应条件
water; sec.-butyllithium 1.) THF, Et2O, pentane, -90 deg C, 3 h, 2.) THF, Et2O, pentane, 30 min; Yield given. Multistep reaction;
参考文献
Seyferth, Dietmar; Mammarella, Robert E.; Klein, Helmut A.
Journal of Organometallic Chemistry, 1980 , vol. 194, # 1 p. 1 - 8
反应条件
2: H2SO4; aqueous acetic acid View Scheme
参考文献
Sommer et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 2932
反应条件
1: 100 percent / KOH / ethanol 2: 90 percent / SOCl2 View Scheme
参考文献
Sommer; Marans
Journal of the American Chemical Society, 1950 , vol. 72, p. 1935,1937,1939
