Pd2(PPh3)2Cl2 in m-xylene=m-xylol byproducts: C6H5CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-Me-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-Cl-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (24 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: m-Me-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-MeO-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
