[RhCl(η2:η2-cycloocta-1,5-diene)]2; potassium carbonate; tris-(dimethylamino)-phosphine; caesium carbonate in toluene T=100°C; 20 h;

potassium carbonate; MgLa mixed oxide; palladium in ethanol T=80°C; Suzuki-Miyaura cross-coupling; 2 h;

tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; water; toluene T=80°C; Suzuki Coupling; Inert atmosphereSonicationReflux;

potassium fluoride; 2'-(dimethylamino)-2-biphenylyl-palladium(II) chloride dinorbornylphosphine complex in 1,4-dioxane T=110°C; Suzuki cross-coupling reaction;

hydrogenchloride T=95°C;

1: With sodium hydroxide in water T=300°C; 1.5 h; Autoclave; 2: With hydrogenchloride in dichloromethane; water pH=7; Product distribution / selectivity;

potassium hydroxide; hydrazine hydrate in diethylene glycol T=115 - 195°C;

1: triethylamine / toluene / 15 h / |Reflux; |Inert atmosphere 2: dimethylsulfide borane complex / dichloromethane / 2 h / 0 °C / |Inert atmosphere 3: toluene / 1 h / 20 °C / |Schlenk technique; |Inert atmosphere 4: toluene; o-di-fluorobenzene / 16 h / 140 °C / |Inert atmosphere 5: potassium hydrogen difluoride / toluene; methanol; water / 2 h / 0 - 20 °C / |Schlenk technique; |Sealed tube; |Cooling; |Inert atmosphere 6: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; water; ethanol / 80 °C / |Inert atmosphere; |Sonication; |Reflux View Scheme

1: LiAlH4 / diethyl ether 2: H2, aq. NaOH / Raney-Ni / ethanol View Scheme

3 h; Heating;