in neat (no solvent) byproducts: Br2, O2; heating Co to 245-250°C, adding under stirring gaseous BrF5, forcing temperature step by step to 400°C; no formation of OF2 and ClF;;
in neat (no solvent) byproducts: Br2, O2; heating CoCl2 to 245-250°C, adding under stirring gaseous BrF5, forcing temperature step by step to 400°C; no formation of OF2 and ClF;;
byproducts: BrF3O; addn. at -196°C, stirred at 20°C for 2.5 h, cooled to -196°C; the noncondensable material distd. off, the voleatile material sept. byfractional distn., the solid nonvolatile product determined by Raman spetr.;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1980 , vol. 19, p. 1494 - 1498
