1-(2-甲氧基苯基)-2-丙炔-1-醇合成路线 （共 9 条）
反应条件
in tetrahydrofuran T=0°C; Grignard reaction;
参考文献
Kazmaier, Uli; Lucas, Simon; Klein, Manuela
Journal of Organic Chemistry, 2006 , vol. 71, # 6 p. 2429 - 2433
反应条件
diethyl ether; ammonia Durchleiten von Acetylen;
参考文献
Rutan; May
Journal of the American Chemical Society, 1947 , vol. 69, p. 2017
反应条件
sodium amide in ammonia
参考文献
Lockhart,I.M.; Tanner,E.M.
Journal of the Chemical Society, 1965 , p. 3610 - 3613
反应条件
sodium hydroxide; n-butyllithium 1.) THF, -78 deg C, 1 h; 2.) methanol, 30 min; 3.) CH2Cl2, 2-3 h, sunlight; Yield given. Multistep reaction;
参考文献
Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Maiorana, Stefano; Papagni, Antonio; Torchio, Maurizio
Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7943 - 7946
反应条件
2.) atmosphere 1.) THF, -15 deg C, 1 h; 2.) CH2Cl2, 2-3 h, sunlight; Yield given. Multistep reaction;
参考文献
Baldoli, Clara; Del Buttero, Paola; Licandro, Emanuela; Maiorana, Stefano; Papagni, Antonio; Torchio, Maurizio
Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7943 - 7946
反应条件
trans-[RuCl2(η3:η3-2,7-dimethylocta-2,6-diene-1,8-diyl)(PPh3)] in water T=60°C; 20 h; Sealed tubeInert atmosphere;
参考文献
Cadierno, Victorio; Francos, Javier; Gimeno, Jose
Organometallics, 2011 , vol. 30, # 4 p. 852 - 862
反应条件
trifluoroacetic acid; [Ru(η3-2-C3H4Me)(CO)(1,1'-(Ph2P)2-ferrocene)][SbF6]
T=75°C; 2 h;
参考文献
Cadierno, Victorio; Gimeno, Jose; Nebra, Noel
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 3 p. 382 - 394
反应条件
carbamic acid 1,1-dimethylethyl ester; [Ru(η3-2-C3H4Me)(CO)(1,1'-(Ph2P)2-ferrocene)][SbF6]; trifluoroacetic acid in tetrahydrofuran
T=20 - 75°C; Inert atmosphere;
参考文献
Cadierno, Victorio; Gimeno, Jose; Nebra, Noel
Journal of Heterocyclic Chemistry, 2010 , vol. 47, # 1 p. 233 - 236
反应条件
indium(III) chloride in water
T=160°C; Meyer-Schuster rearrangement; 0.166667 h; Microwave irradiation; stereoselective reaction;
参考文献
Cadierno, Victorio; Francos, Javier; Gimeno, Jose
Tetrahedron Letters, 2009 , vol. 50, # 33 p. 4773 - 4776
