1: Cs2CO3 / Pd(PPh3)4 / dimethylformamide / 110 °C 2: BBr3 / CH2Cl2 / 0 - 20 °C View Scheme
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Yin, Hang; Lee, Gui-In; Hyung, Soon Park; Payne, Gregory A.; Rodriguez, Johanna M.; Sebti, Said M.; Hamilton, Andrew D.
Angewandte Chemie - International Edition, 2005 , vol. 44, # 18 p. 2704 - 2707
tris(dibenzylideneacetone)dipalladium (0); (S)-(6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl)bis[bis(3,5-di-tert-butyl-phenyl)-phosphine]; N-ethyl-N,N-diisopropylamine in tetrahydrofuran T=70°C; 168 h;
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N,N,N',N'-tetra-methylnaphthalene-1,8-diamine; tris-(dibenzylideneacetone)dipalladium(0); (R)-(+)-2,2'-bis(diphenylphosphino)-3,3'-bi(benzo[b]thiophen) in N,N-dimethyl-formamide T=90°C; Arylation; Heck reaction; 18 h; Title compound not separated from byproducts;
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