pyridine; hydrogen; palladium diacetate; 1,3-bis-(diphenylphosphino)propane in N,N-dimethyl-formamide T=80°C; P=15001.5 Torr; 60 h;

PEPPSITM-IPr; lithium bromide in tetrahydrofuran; 10,11-dihydro-5-[3-(methylamino)propyl]-5H-dibenz(b,f)azepin T=25°C; Negishi cross-coupling; 2 h; Inert atmosphere; chemoselective reaction;

tetra-n-butylammonium tetrafluoroborate; bis-triphenylphosphine-palladium(II) chloride in N,N-dimethyl-formamide T=90°C; electrochemical reaction;

2,6-di-tert-butyl-4-methyl-phenol; triphenylphosphine; lithium chloride; tetrakis(triphenylphosphine) palladium(0); copper(I) bromide in 1,4-dioxane Heating;