3,5-二溴-1-三甲基硅基苯合成路线 （共 9 条）
反应条件
in diethyl ether; hexane T=20°C; silylation; 1 h;
参考文献
Rehm, J. D. Daniel; Ziemer, Burghard; Szeimies, Guenter
European Journal of Organic Chemistry, 1999 , # 9 p. 2079 - 2085
反应条件
1: 1,3,5-tribromo benzene With n-butyllithium in tetrahydrofuran; hexane; toluene T=-78°C; 0.25 h; Inert atmosphere; 2: tetramethylsilane in tetrahydrofuran; hexane; toluene T=-78 - 20°C; Inert atmosphere;
参考文献
Graff, Julien; Debande, Thibaut; Praz, Jezabel; Guenee, Laure; Alexakis, Alexandre
Organic Letters, 2013 , vol. 15, # 16 p. 4270 - 4273
反应条件
n-butyllithium; chloro-trimethyl-silane; triethylamine in tetrahydrofuran; methanol
参考文献
US2013/119367 A1, ;
Page/Page column ;
反应条件
n-butyllithium dann mit Chlor-trimethyl-silan;
参考文献
Journal of the American Chemical Society, , vol. 80, p. 5289,5293
反应条件
magnesium 1.) THF, RT, 2 h, 2.) THF, reflux, 30 min; Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organometallic Chemistry, , vol. 225, # 1 p. 203 - 210
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethanol; toluene 6 h; Heating;
参考文献
Miller, Timothy M.; Neenan, Thomas X.; Zayas, Roberto; Bair, Harvey E.
Journal of the American Chemical Society, 1992 , vol. 114, # 3 p. 1018 - 1025
反应条件
1: 80 percent / Pd(PPh3)4; aq. K2CO3 / tetrahydrofuran / 24 h / Heating 2: BBr3 3: aq. KOH View Scheme
参考文献
Gong; Hu; Pu
Journal of Organic Chemistry, 2001 , vol. 66, # 7 p. 2358 - 2367
反应条件
n-butyllithium in diethyl ether; hexane T=-78°C; 0.5 h;
参考文献
Chen, Grace J.; Tamborski, Christ
Journal of Organometallic Chemistry, 1983 , vol. 251, # 2 p. 149 - 158
反应条件
iodine cloride in dichloromethane T=0°C; 2.16667 h;
参考文献
Bo, Zhishan; Schlueter, A. Dieter
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5327 - 5332
