(二甲基(苯基)甲硅烷基)甲醇合成路线 （共 7 条）
反应条件
1: (hydroxymethyl)dimethylphenylsilane With potassium tert-butylate; N,N,N',N'-tetramethyl-urea T=20 - 25°C; Brook rearrangement; 2: 3,5-dinitrobenzoic acid chloride With pyridine in tetrahydrofuran T=50°C; 1.5 h;
参考文献
Simov, Biljana Peric; Wuggenig, Frank; Mereiter, Kurt; Andres, Hendrik; France, Julien; Schnelli, Peter; Hammerschmidt, Friedrich
Journal of the American Chemical Society, 2005 , vol. 127, # 40 p. 13934 - 13940
参考文献
Boons; Elie; Van der Marel; Van Boom
Tetrahedron Letters, 1990 , vol. 31, # 15 p. 2197 - 2200
反应条件
1: With dihydrogen peroxide; sodium hydrogencarbonate in tetrahydrofuran
T=50°C; 5 h;
2: With 2,2-bis(hydroxymethyl)-1,3-propanediol; water in tetrahydrofuran
参考文献
Simov, Biljana Peric; Wuggenig, Frank; Mereiter, Kurt; Andres, Hendrik; France, Julien; Schnelli, Peter; Hammerschmidt, Friedrich
Journal of the American Chemical Society, 2005 , vol. 127, # 40 p. 13934 - 13940
反应条件
1: With dihydrogen peroxide; sodium hydrogencarbonate in tetrahydrofuran
T=50°C;
2: With 2,2-bis(hydroxymethyl)-1,3-propanediol in tetrahydrofuran; water
参考文献
Simov, Biljana Peric; Wuggenig, Frank; Mereiter, Kurt; Andres, Hendrik; France, Julien; Schnelli, Peter; Hammerschmidt, Friedrich
Journal of the American Chemical Society, 2005 , vol. 127, # 40 p. 13934 - 13940
反应条件
air in diethyl ether
T=20°C;
参考文献
Nobe, Youhei; Arayama, Kyohei; Urabe, Hirokazu
Journal of the American Chemical Society, 2005 , vol. 127, # 51 p. 18006 - 18007
反应条件
methanol; p-toluenesulfonyl chloride
1 h; Heating;
参考文献
Kabachnik, M. I.; Zakharov, L. S.; Molchanova, G. N.; Drozdova, T. D.; Petrovskii, P. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 7.2 p. 1527 - 1532
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 38, # 7 p. 1664 - 1670
反应条件
Multistep reaction.;
参考文献
Kapeller, Dagmar C.; Brecker, Lothar; Hammerschmidt, Friedrich
Chemistry - A European Journal, 2007 , vol. 13, # 34 p. 9582 - 9588
