trichlorosilane; dihydrogen hexachloroplatinate T=70 - 100°C; 5 h;

(S)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl; bis(η3-allyl-μ-chloropalladium(II)); trichlorosilane T=40°C; 24 h; Yields of byproduct given. Title compound not separated from byproducts;

1: 42.4 percent / diethyl ether / 3 h / Heating 2: 74 percent / trichlorosilane / 0.1 M H2PtCl6*6H2O in abs. i-PrOH / 5 h / 70 - 100 °C View Scheme

(S)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl; bis(η3-allyl-μ-chloropalladium(II)); trichlorosilane T=40°C; 24 h; Yield given. Yields of byproduct given;

1: With potassium fluoride; potassium hydrogencarbonate in tetrahydrofuran; methanol T=20°C; Tamao oxidation; 1 h; In air; 2: With dihydrogen peroxide in tetrahydrofuran; methanol; water T=20°C; Tamao oxidation;