顺 -1,2-环己二醇合成路线 (共 184 条)
反应条件
water; 4-methylmorpholine N-oxide; osmium; Cu-Al-hydrotalcite in toluene T=60°C; 4.5 h;
参考文献
Huang, Yangen; Meng, Wei-Dong; Qing, Feng-Ling
Tetrahedron Letters, 2004 , vol. 45, # 9 p. 1965 - 1968
反应条件
lithium aluminium tetrahydride in diethyl ether 2 h;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 822 - 827
反应条件
rhodium contaminated with carbon; hydrogen in n-heptane T=119.84°C; P=51005.1 Torr; 4 h; AutoclaveInert atmosphere; Reagent/catalyst;
参考文献
Applied Catalysis A: General, , vol. 468, p. 418 - 425
反应条件
18-crown-6 ether; tert-butylamine; tert-butyl alcohol; potassium in tetrahydrofuran T=20°C; 2 h;
参考文献
Shi, Lei; Wu, Jiong Xia; Fu, Min Zhang; Yong, Qiang Tu
Synlett, 2002 , # 9 p. 1505 - 1507
反应条件
cis-[Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)O2(trifluoroacetate)]ClO4 in acetonitrile T=20°C; 14 h;
参考文献
Journal of the American Chemical Society, , vol. 127, # 41 p. 14239 - 14249
反应条件
1: With sodium periodate; acetic acid; lithium bromide T=80°C; Prevost-Woodward reaction; 36 h; 2: With potassium carbonate in methanol T=25°C; 24 h;
参考文献
Emmanuvel, Lourdusamy; Ali Shaikh, Tanveer Mahammad; Sudalai, Arumugam
Organic Letters, 2005 , vol. 7, # 22 p. 5071 - 5074
反应条件
ethanol; nickel T=175°C; P=88260.9 Torr; Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 54, p. 1651,1658
Nippon Kagaku Kaishi, , vol. 52, p. 585,587
Chem.Abstr., , p. 5084
反应条件
cis-[Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)O2(trifluoroacetate)]ClO4 in water; tert-butyl alcohol T=20°C; 14 h;
参考文献
Journal of the American Chemical Society, , vol. 127, # 41 p. 14239 - 14249
反应条件
1: in benzene 1 h; Inert atmosphereIrradiation; 2: With sodium hydroxide in methanol T=20°C; 1 h;
参考文献
Sebej, Peter; Solomek, Tomas; Hroudna, L'ubica; Brancova, Pavla; Klan, Petr
Journal of Organic Chemistry, 2009 , vol. 74, # 22 p. 8647 - 8658
反应条件
ethanol; nickel T=175°C; P=88260.9 Torr; Hydrogenation;
参考文献
Journal of the American Chemical Society, , vol. 54, p. 1651,1658
Nippon Kagaku Kaishi, , vol. 52, p. 585,587
Chem.Abstr., , p. 5084