1: With n-butyllithium; bipyridine in tetrahydrofuran; hexane T=-78°C; 2: With tri-isopropoxy-borane in tetrahydrofuran; diethyl ether; hexane T=-78 - 20°C; Further stages.;
参考文献
Journal of Organic Chemistry, , vol. 67, # 20 p. 7110 - 7123
1: 1-bromo-3-methyl-benzene With n-butyllithium in tetrahydrofuran; hexane T=-78 - -10°C; 2: tri-isopropoxy-borane in tetrahydrofuran; hexane T=-78 - 20°C;
参考文献
Lloyd, David G.; Hughes, Rosario B.; Zisterer, Daniela M.; Williams, D. Clive; Fattorusso, Caterina; Catalanotti, Bruno; Campiani, Giuseppe; Meegan, Mary J.
Journal of Medicinal Chemistry, 2004 , vol. 47, # 23 p. 5612 - 5615
tetra-2-pyridinylpyrazine; [Ir(I)(salicylidenebenzyliminato)(1,5-cyclooctadiene)] in dichloromethane; toluene under Ar; mixt. was heated at 80°C for 21 h in sovent mixt.; solvent removed under reduced pressure, Et2O was added, after 10percent aq. HCl was added, mixt. stirred for 4 h, organic layer dried with MgSO4, solvent was removed under reduced pressure, residue was chromd. (flash chromy, SiO2); NMR (m:p=1.5:1); 62percent total;
参考文献
Journal of Organometallic Chemistry, , vol. 692, # 20 p. 4244 - 4250
1: With n-butyllithium in tetrahydrofuran T=-78°C; 2 h; Inert atmosphere; 2: With boric acid trimethyl ester in tetrahydrofuran T=-78 - 20°C; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran
参考文献
Journal of the American Chemical Society, , vol. 132, # 40 p. 14006 - 14008
copper(I) bromide in not given Li educt added to CuBr slurry in ether at 0°C under N2, reacted for 10 min, B2H6 soln. added, stirred for 18 h at room temp.; hydrolyzed with H2O, then with aq. NaOH, extd. with ether, aq. phase acidified with aq. HCl, extd. with ether, exts. dried (MgSO4), ether removed, solid recrystd. (petroleum ether);
参考文献
Bullen, N. P.; Chiheru, K. S.; Thorpe, F. G.
Journal of Organometallic Chemistry, 1980 , vol. 195, # 2 p. 147 - 154
