1 - 萘基三乙氧基硅烷合成路线 （共 11 条）
反应条件
1: naphthalene-1-diazonium tosylate With [RhCl(η2:η2-cycloocta-1,5-diene)]2; tetra-(n-butyl)ammonium iodide; triethylamine in N,N-dimethyl-formamide T=20°C; Sandmeyer reaction; 2 h; Inert atmosphere; 2: 4-bromooctafluorobutanetriethoxysilane in N,N-dimethyl-formamide T=20 - 100°C; Inert atmosphere;
参考文献
Tang, Zhi Yong; Zhang, Yuan; Wang, Tao; Wang, Wei
Synlett, 2010 , # 5 art. no. W16209ST, p. 804 - 808
反应条件
1: 1-Bromonaphthalene With magnesium; ethylene dibromide in tetrahydrofuran T=25°C; Sonication; 2: ethyl orthosilicate in tetrahydrofuran T=25°C; 0.75 h; Sonication;
参考文献
Jorapur, Yogesh R.; Shimada, Toyoshi
Synlett, 2012 , vol. 23, # 7 p. 1064 - 1068
反应条件
addn. of (C10H7)Li to Si(OC2H5)4;;
参考文献
Gmelin Handbook: Si: MVol.C, 78, page 217 - 218
参考文献
Fox, Marye Anne; Nobs, Frederic J.; Voynick, Tamara A.
Journal of the American Chemical Society, 1980 , vol. 102, # 12 p. 4029 - 4036
反应条件
addn. of Si(OC2H5)4 to (C10H7)Li;;
参考文献
Gmelin Handbook: Si: MVol.C, 78, page 217 - 218
反应条件
1: diethyl ether 2: C2H5OH View Scheme
参考文献
Melzer, W.
Ber., 1908 , vol. 41, p. 3390 - 3395
参考文献
Khotinsky, E.; Seregenkov, B.
Ber., 1908 , vol. 41, p. 2946 - 2953
Full Text Show Details
Gmelin Handbook: Si: MVol.C, 78, page 217 - 218
参考文献
Melzer, W.
Ber., 1908 , vol. 41, p. 3390 - 3395
Full Text Show Details
Gmelin Handbook: Si: MVol.C, 78, page 217 - 218
参考文献
Khotinsky; Seregenkoff
Chemische Berichte, 1908 , vol. 41, p. 2951
反应条件
2,6-dimethylpyridine; 1-(chloromethyl)-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate); silver(l) oxide in acetone T=23 - 90°C; 2 h; regioselective reaction;
参考文献
Tang, Pingping; Ritter, Tobias
Tetrahedron, 2011 , vol. 67, # 24 p. 4449 - 4454
