hydrogenchloride; hydrogen; platinum(IV) oxide in water

hydrogen; triethylamine; [(S,S)-Et-BPE]Rh(COD)+BF4- in methanol T=24°C; P=2585.81 Torr; 40 h; Product distribution / selectivity;

1: With sodium hydroxide in tetrahydrofuran; water T=20°C; 1 h; 2: With hydrogenchloride in water pH=1;

triethylamine in dichloromethane T=5 - 20°C; 1 h;

hydrogen; triethylamine P=2585.81 Torr; 16 h; Product distribution / selectivity;

1.1: anhydrous zinc trifluoromethanesulfonate; chiral 4-tert-butyl-4,5-dihydro-1,3-oxazole-based reagent / toluene / 10 - 20 °C 1.2: toluene / 26 h / 10 °C 1.3: magnesium monoperoxyphthalate hexahydrate / methanol / 0 °C 2.1: periodic acid / diethyl ether / 0 °C View Scheme

暂无反应条件数据

1: trichloroisocyanuric acid / dichloromethane / 3 h / 5 - 20 °C 2: triethylamine / dichloromethane / 1 h / 5 - 20 °C View Scheme

1: water / 108 h / 20 °C 2: alcohol dehydrogenase from Lactobacillus brevis; 12-oxophytodienoic acid reductase isoenzyme OPR1-wt from Lycopersicon esculentum / isopropyl alcohol; aq. phosphate buffer / 22 h / 30 °C / pH 7.5 / |Enzymatic reaction 3: palladium on carbon / isopropyl alcohol / 4 h / 30 °C View Scheme