in neat (no solvent, gas phase) byproducts: SiCl4, toluene, benzyl chloride; pyrolysis of C6H5CH2OSiCl3 and HSiCl3 (ratio 1:3) at 580°C; distn. of the condensate (110-130°C); further products: HCl2SiOSiCl2OSiCl3, HCl2Si(OSiCl2)2OSiCl3, C6H5CH2SiCl3, C6H5CH2(OSiCl2)2OSiCl3 and C6H5CH2OSiCl2OSiCl3;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 60, p. 952 - 957
Zhurnal Obshchei Khimii, , vol. 60, p. 1078 - 1083
in neat (no solvent, gas phase) mixt. of SiCl4 and PhCH2OSiCl3 are passed through empty quartz tube heated to 620°C (20-30 sec stayed in reaction zone, gas phase reaction), further product: Cl3SiOSiCl2OSiCl3 (10.5percent);
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 57, p. 1142 - 1146
Zhurnal Obshchei Khimii, , vol. 57, p. 1275 - 1280
trichlorosilane T=480°C; 0.00833333 h; other amount of HSiCl3, other temperature; Product distributionMechanism;
参考文献
Chernyshev, E. A.; Krasnova, T. L.; Mudrova, N. A.; Petrunin, A. B.; Turkel'taub, G. N.
J. Gen. Chem. USSR (Engl. Transl.), 1990 , vol. 60, # 5 p. 1078 - 1083,952 - 957
Chernyshev, E. A.; Mudrova, N. A.; Krasnova, T. L.; Tarasova, T. N.; Chernyshev, A. E.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 6 p. 1275 - 1280,1142 - 1146
T=620°C; 0.00833333 h; copyrolysis; other temperature of the reaction zone; Product distribution;
参考文献
Chernyshev, E. A.; Mudrova, N. A.; Krasnova, T. L.; Tarasova, T. N.; Chernyshev, A. E.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 6 p. 1275 - 1280,1142 - 1146
T=620°C; 0.0111111 h; var. of temperature; Product distributionMechanism;
参考文献
Chernyshev, E. A.; Krasnova, T. L.; Mudrova, N. A.; Golovkin, A. V.; Kuznetsova, M. G.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 8 p. 1725 - 1730,1539 - 1543
