1-碘-2-三甲基硅基乙炔合成路线 （共 14 条）
反应条件
1: ortho-cresol With n-butyllithium; gallium(II) chloride in hexane; chlorobenzene
T=20°C; 0.166667 h;
2: 1-iodo-2-trimethylsilylethyne With 2,6-di-tert-butyl-4-methylpyridine in hexane; chlorobenzene
Further stages.;
参考文献
Kobayashi, Katsumi; Arisawa, Mieko; Yamaguchi, Masahiko
Journal of the American Chemical Society, 2002 , vol. 124, # 29 p. 8528 - 8529
反应条件
copper(I) bromide in tetrahydrofuran; diethyl ether
1.) -40 deg C, 45 min; 2.) -15 deg C, 2 h;
参考文献
Commercon, A.; Normant, J. F.; Villieras, J.
Tetrahedron, 1980 , vol. 36, # 82 p. 1215 - 1222
反应条件
N,N,N',N,-tetramethylethylenediamine
参考文献
Normant,J.F. et al.
Tetrahedron Letters, 1975 , p. 1465 - 1468
反应条件
diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide
参考文献
THE UNIVERSITY OF HONG KONG
Patent: WO2007/90343 A1, 2007 ;
Location in patent: Page/Page column 18 ;
