trichlorophosphate

Behandeln des Reaktionsgemisches mit Wasser;

Behandeln des Reaktionsgemisches mit Wasser;

lead(IV) acetate 1.) benzene, 60 deg C, 7 h, 2.) CHCl3-MeOH, 2 d, r.t.; Yield given. Multistep reaction;

1: 1.) Pb(OAc)4 / 1.) benzene, 60 deg C, 7 h, 2.) CHCl3-MeOH, 2 d, r.t. 2: 26 mg / K2CO3 / acetone View Scheme

1: 1.) phosphorus oxychloride / 1.) RT, 30 min, 2.) 100 deg C, 2 h 2: 98 percent / sodium chlorite, dibasic sodium phosphate, 2-methyl-2-butene / 2-methyl-propan-2-ol; H2O / 0.5 h / Ambient temperature 3: 85 percent / nitric acid / 0.17 h / 0 °C 4: 95 percent / hydrogen / platinum oxide / 2 h / 2068.6 Torr 5: 78 percent / sodium hydroxide / toluene / 0 °C 6: 88 percent / sodium hydride / N,N-dimethyl-acetamide / 1.) RT, 12 h, 2.) 30 min 7: diisopropylamine, n-butyllithium / tetrahydrofuran; hexane / 1.) -78 deg C, 90 min, 2.) RT, 90 min 8: 28 percent / palladium-on-charcoal / xylene / 1 h / Heating View Scheme

1: 1.) phosphorus oxychloride / 1.) RT, 30 min, 2.) 100 deg C, 2 h 2: 98 percent / sodium chlorite, dibasic sodium phosphate, 2-methyl-2-butene / 2-methyl-propan-2-ol; H2O / 0.5 h / Ambient temperature View Scheme

n-butyllithium

trichlorophosphate 1.) 35-38 deg C, 5 h, 2.) 50 deg C, 1.5 h; Yield given. Title compound not separated from byproducts;

trichlorophosphate