反应条件
1: 95 percent / PPh3; Et3N / Pd2dba3*CHCl3 / tetrahydrofuran / 12 h / 20 °C
2: 73 percent / MCPBA / CH2Cl2 / 44 h / 20 °C
3: 67 percent / DBU; ozone / tetrahydrofuran / 3 h / -78 - 20 °C
4: 62 percent / PPh3; DEAD / tetrahydrofuran / 6 h / 0 °C
5: 79 percent / DIBAL-H / CH2Cl2; hexane / 1 h / -78 °C
6: 89 percent / OsO4; NMO / acetone; H2O / 12 h / 20 °C
7: 71 percent / pyridine / 10 h / 20 °C
8: 71 percent / TsOH*H2O / 6 h / 20 °C
9: 61 percent / FeCl3*6H2O/SiO2 / CH2Cl2 / 15 h / 20 °C
10: 95 percent / pyridine / 10 h / 20 °C
11: 60 percent / DMF; SOCl2 / pyridine / 8 h / 20 °C
12: 73 percent / NH3 / methanol / 192 h / 20 °C
13: 91 percent / 1 M aq. HCl / 6 h / 80 °C
View Scheme
参考文献
Trost, Barry M.; Madsen, Robert; Guile, Simon D.
Tetrahedron Letters, 1997 , vol. 38, # 10 p. 1707 - 1710
