in 1,4-dioxane; water T=24.84°C; KineticsThermodynamic data; Temperature;

1: With (4-(but-3-en-1-yl)phenyl)diphenylphosphine; bis(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononyl)diazo dicarboxylate in tetrahydrofuran T=20°C; Mitsunobu reaction; Inert atmosphere; 2: With 1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl iodide; C30H26N6Ru(2+)*2Cl(1-); sodium L-ascorbate in methanol; acetonitrile 2.5 h; Inert atmosphereIrradiation;

sodium hydroxide

sodium hydroxide

1: concentrated sulfuric acid 2: hydrogen chloride / 270 - 275 °C View Scheme