1-（1-（4-氯苯基）乙烯基）苯合成路线 （共 36 条）
反应条件
1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 2 h; 2: para-chloroacetophenone in tetrahydrofuran; hexane T=-70°C; 10 h; 3: With toluene-4-sulfonic acid in dichloromethane T=20°C; 10 h;
参考文献
Han, Peng; Wang, Ruji; Wang, David Zhigang
Tetrahedron, 2011 , vol. 67, # 46 p. 8873 - 8878
反应条件
sodium carbonate; Pd-montmorillonite in 1-methyl-pyrrolidin-2-one T=150°C; Heck reaction; 2 h;
参考文献
Molnar, Arpad; Papp, Attila
Synlett, 2006 , # 18 p. 3130 - 3134
反应条件
[(N-di(2-pyridyl)methyl-N'-cyclohexylurea)PdCl2]; diisopropylamine in 1-methyl-pyrrolidin-2-one; water T=160°C; Heck-Mizoroki reaction; 32 h;
参考文献
Varma, Rajender S.; Naicker, Kannan P.; Liesen, Per J.
Tetrahedron Letters, 1999 , vol. 40, # 11 p. 2075 - 2078
反应条件
[(N-di(2-pyridyl)methyl-N'-cyclohexylurea)PdCl2]; tetrabutylammomium bromide; diisopropylamine in 1-methyl-pyrrolidin-2-one; water T=160°C; Heck-Mizoroki reaction; 47 h;
参考文献
Najera, Carmen; Gil-Molto, Juan; Karlstroem, Sofia; Falvello, Larry R.
Organic Letters, 2003 , vol. 5, # 9 p. 1451 - 1454
反应条件
tetrakis(triphenylphosphine) palladium(0); oxygen; copper(l) chloride; lithium tert-butylate in 1,4-dioxane T=70°C; 9 h;
参考文献
Zhao, Xia; Jing, Jing; Lu, Kui; Zhang, Yan; Wang, Jianbo
Chemical Communications, 2010 , vol. 46, # 10 p. 1724 - 1726
反应条件
1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane; dnpf; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=80°C; Heck Reaction; 18 h; Inert atmosphere;
参考文献
Zou, Yinjun; Qin, Liena; Ren, Xinfeng; Lu, Yunpeng; Li, Yongxin; Zhou, Jianrong
Chemistry - A European Journal, 2013 , vol. 19, # 10 p. 3504 - 3511
反应条件
[(N-di(2-pyridyl)methyl-N'-cyclohexylurea)PdCl2]; tetrabutylammomium bromide; diisopropylamine in 1-methyl-pyrrolidin-2-one; water T=160°C; Heck-Mizoroki reaction; 150 h;
参考文献
Najera, Carmen; Gil-Molto, Juan; Karlstroem, Sofia; Falvello, Larry R.
Organic Letters, 2003 , vol. 5, # 9 p. 1451 - 1454
反应条件
[hetba]Br; palladium (II) bromide in 1-methyl-pyrrolidin-2-one T=160°C; decarbonylative Heck olefination; 16 h;
参考文献
Goossen, Lukas J.; Paetzold, Jens
Angewandte Chemie - International Edition, 2004 , vol. 43, # 9 p. 1095 - 1098
反应条件
[1-butyl-3-methylimidazolium][Sb2F11] T=90°C; Friedel-Crafts alkenylation reaction; 0.333333 h;
参考文献
Choi, Doo Seong; Kim, Jin Hong; Shin, Ueon Sang; Deshmukh, Ravindra R.; Song, Choong Eui
Chemical Communications, 2007 , # 33 p. 3482 - 3484
反应条件
[Rh(C2H4)2Cl]2 in xylene Mizoroki-Heck reaction; 4 h; Heating; Title compound not separated from byproducts;
参考文献
Sugihara, Toru; Satoh, Tetsuya; Miura, Masahiro; Nomura, Masakatsu
Advanced Synthesis and Catalysis, 2004 , vol. 346, # 13-15 p. 1765 - 1772
