反应条件
1.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
2.1: benzene / |Irradiation
3.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
3.2: 2 h / 3 - 20 °C
4.1: RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN]; hydrogen; potassium tert-butylate / isopropyl alcohol / 40 h / 25 °C / 5171.62 Torr / |Glovebox
5.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
6.1: dimethylsulfoxide-d6 / 0.5 h
7.1: aq. buffer / 0.25 h / |Inert atmosphere; |Irradiation
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
