2-(3-环己烯基)乙醇合成路线 （共 20 条）
反应条件
magnesium; palladium on activated charcoal in methanol Ambient temperature;
参考文献
Olah, George A.; Prakash, G. K. Surya; Arvanaghi, Massoud; Bruce, Mark R.
Angewandte Chemie, 1981 , vol. 93, # 1 p. 107
反应条件
sodium tetrahydroborate; 2-methyl-but-2-ene; boron trifluoride diethyl etherate in tetrahydrofuran
T=0 - 20°C; 3 h; Inert atmosphere;
参考文献
Proto, Stefano; Amat, Mercedes; Perez, Maria; Ballette, Roberto; Romagnoli, Federica; Mancinelli, Andrea; Bosch, Joan
Organic Letters, 2012 , vol. 14, # 15 p. 3916 - 3919
反应条件
3-chloro-benzenecarboperoxoic acid in N,N-dimethyl-formamide
6 h; Ambient temperature;
参考文献
Tamao, K.; Kakui, T.; Akita, M.; Iwahara, T.; Kanatani, R.; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 983 - 990
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
4 h; Heating;
参考文献
Lednicer; Von Voigtlander; Emmert
Journal of Medicinal Chemistry, 1981 , vol. 24, # 4 p. 404 - 408
反应条件
ammonium cerium(IV) nitrate
参考文献
Trahanovsky,W.S. et al.
Journal of the American Chemical Society, 1969 , vol. 91, # 18 p. 5068 - 5072
反应条件
oxygen; tri-isobutyl aluminium; zirconocene dichloride
1.) (CH2Cl)2, 0 deg C, 24 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Negishi, Ei-ichi; Yoshida, Tadao
Tetrahedron Letters, 1980 , vol. 21, p. 1501 - 1504
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
30 h; Heating; Yield given. Yields of byproduct given;
参考文献
Yadav, Veejendra; Fallis, Alex G.
Canadian Journal of Chemistry, 1991 , vol. 69, # 5 p. 779 - 789
反应条件
1: 100 percent / LiAlH4 / diethyl ether / a) 22 deg C, 12 h, b) reflux, 4 h
2: 84 percent / Br2, PPh3 / benzene / 6 h / 22 °C
3: 92 percent / aq. ethanol / 16 h / Heating
4: 100 percent / DIBAL / hexane / a) -78 deg C, 30 min, b) 3 h
5: 44 percent / 4 A molecular sieves / benzene
6: 12 percent / n-Bu3SnH, AIBN / benzene / 30 h / Heating
View Scheme
参考文献
Yadav, Veejendra; Fallis, Alex G.
Canadian Journal of Chemistry, 1991 , vol. 69, # 5 p. 779 - 789
反应条件
1: 84 percent / Br2, PPh3 / benzene / 6 h / 22 °C
2: 92 percent / aq. ethanol / 16 h / Heating
3: 100 percent / DIBAL / hexane / a) -78 deg C, 30 min, b) 3 h
4: 44 percent / 4 A molecular sieves / benzene
5: 12 percent / n-Bu3SnH, AIBN / benzene / 30 h / Heating
View Scheme
参考文献
Yadav, Veejendra; Fallis, Alex G.
Canadian Journal of Chemistry, 1991 , vol. 69, # 5 p. 779 - 789
反应条件
1: 44 percent / 4 A molecular sieves / benzene
2: 12 percent / n-Bu3SnH, AIBN / benzene / 30 h / Heating
View Scheme
参考文献
Yadav, Veejendra; Fallis, Alex G.
Canadian Journal of Chemistry, 1991 , vol. 69, # 5 p. 779 - 789
