二环[2.2.1]己-乙基三氯硅烷合成路线 （共 7 条）
反应条件
trichlorosilane; tetra-n-butyl phosphonium chloride T=180°C; 12 h;
参考文献
US2004/82803 A1, ;
Page 5 ;
反应条件
hydrogen; palladium in tetrahydrofuran P=760 Torr;
参考文献
Journal of the American Chemical Society, , vol. 102, # 9 p. 3267 - 3269
反应条件
methyl-ethyl phosphite; trichlorosilane; palladium diacetate in toluene T=85 - 95°C; 5 h; Inert atmosphere;
参考文献
US2014/121398 A1, ;
Paragraph 0069; 0070; 0071 ;
反应条件
2: hydrogen / palladium-black / tetrahydrofuran / 760 Torr View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, # 9 p. 3267 - 3269
反应条件
trichlorosilane; dihydrogen hexachloroplatinate T=30 - 40°C; 3 h;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 31, # 4 p. 1199 - 1208,1109 - 1117
反应条件
1: CuF2*2H2O / diethyl ether / 12 h / Ambient temperature 2: 62 percent / MCPBA / dimethylformamide / 3 h / Ambient temperature View Scheme
参考文献
Tamao, K.; Kakui, T.; Akita, M.; Iwahara, T.; Kanatani, R.; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 983 - 990
反应条件
1: 71 percent / CuF2*2H2O / diethyl ether / 12 h / Ambient temperature 2: 68 percent / MCPBA / dimethylformamide / 3 h / Ambient temperature View Scheme
参考文献
Tamao, K.; Kakui, T.; Akita, M.; Iwahara, T.; Kanatani, R.; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 983 - 990
