NaOH in water byproducts: C2H5OH; heating of (CH3)2Si(OC2H5)2, (CH3)3Si(OC2H5) and an excess (50percent) of H2O in presence of NaOH; sepn. of C2H5OH by distn.; boiling of the residue with 20percent aq. HCl; further products;; distn.;;
参考文献
Hunter, M. J.; Warrick, E. L.; Hyde, J. F.; Currie, C. C.
Journal of the American Chemical Society, 1946 , vol. 68, p. 2284 - 2290
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Gmelin Handbook: Si: MVol.C, 103, page 282 - 285
NaOH in water byproducts: C2H5OH; heating of (CH3)2Si(OC2H5)2, (CH3)3Si(OC2H5) and an excess (50percent) of H2O in presence of NaOH; sepn. of C2H5OH by distn.; boiling of the residue with 20percent aq. HCl; further products;; distn.;;
参考文献
Hunter, M. J.; Warrick, E. L.; Hyde, J. F.; Currie, C. C.
Journal of the American Chemical Society, 1946 , vol. 68, p. 2284 - 2290
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.C, 103, page 282 - 285
bis(trichlorophosphine)iminium hexachlorophosphate in 1,1,2,2-tetrachloroethylene; n-heptane T=25°C; various reagent concentrations, other reagent; Rate constant;
参考文献
Chojnowski, Julian; Cypryk, Marek; Fortuniak, Witold; Kazmierski, Krzysztof; Taylor, Richard G.
Journal of Organometallic Chemistry, 1996 , vol. 526, # 2 p. 351 - 361
water byproducts: C2H5OH; addn. of H2O that contained NaOH to a mixt. of (CH3)2Si(OC2H5)2 and (CH3)3Si(OC2H5) (1:1 mol) at 40°C; boiling after addn. of a 20percent excess of H2O;; evapn. of C2H5OH; distillation gives linear polymers (CH3)3Si((CH3)2SiO)(0-13)Si(CH3)3; higher polymers as residue (not distillable);;
参考文献
Gmelin Handbook: Si: MVol.C, 153, page 419 - 422
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Corning Glass Works
Patent: US2457677 , 1948 ;
C. A., 1949 , p. 4402
Pestunovich, V. A.; Petukhov, L. P.; Rakhlin, V. I.; Shterenberg, B. Z.; Mirskov, R. G.; Voronkov, M. G.
Doklady Chemistry, 1982 , vol. 263, p. 128 - 129
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 263, # 4 p. 904 - 906
