T=600°C; P=20 Torr;

4,4'-di(tert-butyl)-[1,1-biphenyl]yllithium in tetrahydrofuran T=-78°C;

1: 600 °C / 20 Torr 2: sodium borohydride (NaBH4) / ethanol View Scheme

T=600°C; P=20 Torr; 0.0333333 h;

T=600°C; P=20 Torr;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '15517769', constants.ctx, '0')">InI</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1730800', constants.ctx, '0')">dichloromethane</a> <br />T=20&deg;C;&nbsp;0.5&nbsp;h;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11340441', constants.ctx, '0')">indium</a>;&nbsp;<a href="#" onclick="return RXDsubstances(event, this, '1209232', constants.ctx, '0')">chloro-trimethyl-silane</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '741857', constants.ctx, '0')">acetonitrile</a> <br />3.5&nbsp;h;&nbsp;&nbsp;Heating;&nbsp;<br /> &nbsp;

<b>With</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '11340441', constants.ctx, '0')">indium</a>&nbsp;<b>in</b>&nbsp; <a href="#" onclick="return RXDsubstances(event, this, '1730800', constants.ctx, '0')">dichloromethane</a> <br />1&nbsp;h;&nbsp;&nbsp;RefluxInert atmosphere;&nbsp;<br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: 1.) Na / 1.) dioxane, reflux, 2 h, 2.) dioxane, a) RT, 1 h, b) 60 deg C, 30 min<br />2: 75 percent / AlBr₃ / CH₂Cl₂ / 0.5 h / 0 &deg;C<br /> <br /> &nbsp;

<b>Multi-step reaction with 2 steps<br /> </b>1: 1.) NaBH₄, 2.) AlCl₃ / 1.) CH₃CN, reflux, 1 h, 2.) CH₃CN, reflux, 0.5 h<br />2: 1.) NaBH₄, 2.) AlCl₃ / 1.) CH₃CN, reflux, 1 h, 2.) CH₃CN, reflux, 2.0 h<br /> <br /> &nbsp;