四(三苯基膦)氢化铑(I)合成路线 （共 10 条）
反应条件
acetone in benzene byproducts: C7H6Si2(CH3)3(OCH(CH3)2); (Ar); addn. of 1 equiv. of acetone to 1:2 mixt. of rhodium compd. and phosphine in benzene, stirring at room temp. for 30 min;
参考文献
Organometallics, , vol. 27, # 14 p. 3502 - 3513
反应条件
in deuterated toluene at 210 K; not isolated; detd. by (14)P NMR;
参考文献
European Journal of Inorganic Chemistry, , # 3 p. 327 - 330
反应条件
1: toluene 2: CO / ethanol View Scheme
参考文献
Inorganic Chemistry, , vol. 27, p. 2473 - 2478
反应条件
in benzene byproducts: 2-butene, propene, propane; mixt. of Rh complex and silyl ether in benzene, stirred at 80°C for 4 h; evapd. in vac., analyzed by IR;
参考文献
Organometallics, , vol. 4, p. 1504 - 1508
反应条件
in toluene byproducts: P(C6H5)3; (N2); at room temp.; GLC yields of organic compounds;
参考文献
Organometallics, , vol. 4, p. 857 - 862
反应条件
in toluene byproducts: P(C6H5)3; (N2); at room temp.; GLC yields of organic compounds;
参考文献
Organometallics, , vol. 4, p. 857 - 862
反应条件
in toluene byproducts: P(C6H5)3; (N2); at room temp.; GLC yields of organic compounds;
参考文献
Organometallics, , vol. 4, p. 857 - 862
反应条件
in toluene byproducts: P(C6H5)3; (N2); at room temp.; GLC yields of organic compounds;
参考文献
Organometallics, , vol. 4, p. 857 - 862
反应条件
hydrogenchloride; triphenylphosphine in ethanol byproducts: NH4Cl; according to Johnson, B. F. G., Segal, J. A., J. Chem. Soc., Dalton Trans., 1972, 1268; refluxing/stirring (15 min, CH2Cl2/MeOH 2:1 v/v, bubbling with HCl gas); concn. of mixt., pptn. on addn. of MeOH, CH2Cl2 and PPh3;
参考文献
Khan, M. Ishaque; Agarwala, U. C.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1139 - 1142
反应条件
in benzene-d6 byproducts: ethylene, vinyl chloride, PPh3; under N2; Rh complex and cis-1,2-dichloroethylene mixed in C6D6 at room temp.; detd. by (31)P NMR spectra;
参考文献
Peterson, Alicia A.; Thoreson, Kristen A.; McNeill, Kristopher
Organometallics, 2009 , vol. 28, # 20 p. 5982 - 5991
