三甲基(3-甲基-2-丁烯-1-基)-硅烷合成路线 （共 58 条）
反应条件
magnesium in tetrahydrofuran
Ambient temperature;
参考文献
Dubac, J.; Laporterie, A.; Iloughmane, H.; Pillot, J. P.; Deleris, G.; Dunogues, J.
Journal of Organometallic Chemistry, 1985 , vol. 281, p. 149 - 162
反应条件
sodium in decane
24 h; Heating;
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 265 - 267
反应条件
sodium hydroxide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; water
T=65°C; 10 h;
参考文献
Soderquist; Santiago; Rivera
Tetrahedron Letters, 1990 , vol. 31, # 35 p. 4981 - 4984
反应条件
in tetrahydrofuran
T=-70 - 20°C;
参考文献
Negishi, Ei-ichi; Luo, Fen-Tair; Rand, Cynthia L.
Tetrahedron Letters, 1982 , vol. 23, p. 27 - 30
反应条件
disodium hydrogenphosphate; sodium amalgam in methanol
T=0°C; 1 h; Yield given;
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
lithium; bis(cyclopentadienyl)titanium dichloride; titanium tetrachloride in tetrahydrofuran
Ambient temperature; Yield given;
参考文献
Biran, C.; Dunogues, J.; Calas, R.; Gerval, J.; Tskhovrebachvili, T.
Synthesis, 1981 , # 3 p. 220 - 222
反应条件
1: NaH / xylene / Heating
2: 14 percent / 1.5 h / 5 °C / Irradiation; photolysis in quartz NMR tube with a 45O-W, medium pressure Hanovia Hg lamp
3: 90 percent Chromat. / diethyl ether / 4 h / -40 - -20 °C
View Scheme
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 4 p. 693 - 696
反应条件
1: 1. sodium hydride / 1. 1 h; 2. overnight
2: 68 percent / sodium / decane / 24 h / Heating
View Scheme
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 265 - 267
反应条件
1: 99.2 percent / H2O2 / acetic acid / 2 h / 100 °C
2: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
3: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
4: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
1: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
2: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
3: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
