三甲基(3-甲基-2-丁烯-1-基)-硅烷合成路线 （共 58 条）
反应条件
1: 99.2 percent / azoisobutyrinitrile / 90 °C
2: 99.2 percent / H2O2 / acetic acid / 2 h / 100 °C
3: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
4: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
5: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
参考文献
Hosomi,A. et al.
Chemistry Letters, 1978 , p. 901 - 904
反应条件
lithium in tetrahydrofuran
Ambient temperature; Yield given;
参考文献
Biran, C.; Dunogues, J.; Calas, R.; Gerval, J.; Tskhovrebachvili, T.
Synthesis, 1981 , # 3 p. 220 - 222
参考文献
Birch, Arthur J.; Kelly, Lawrence F.; Narula, Acharan S.
Tetrahedron, 1982 , vol. 38, # 12 p. 1813 - 1824
反应条件
sodium in decane
24 h; Heating; Mechanism;
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 265 - 267
反应条件
sodium in decane
24 h; Heating; Mechanism;
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 265 - 267
反应条件
1: 14 percent / 1.5 h / 5 °C / Irradiation; photolysis in quartz NMR tube with a 45O-W, medium pressure Hanovia Hg lamp
2: 90 percent Chromat. / diethyl ether / 4 h / -40 - -20 °C
View Scheme
参考文献
Tzeng, Dongjaw; Weber, William P.
Journal of Organic Chemistry, 1981 , vol. 46, # 4 p. 693 - 696
反应条件
methanol; ammonium chloride
1) THF, -78 degC, 1 h; 2) 0 deg C, 10 min; Yield given. Multistep reaction;
参考文献
Fleming, Ian; Rowley, Michael; Cuadrado, Purificacion; Gonzalez-Nogal, Ana M.; Pulido, Francisco J.
Tetrahedron, 1989 , vol. 45, # 2 p. 413 - 424
反应条件
magnesium
Multistep reaction;
参考文献
Hamana, Hiroshi; Sugasawa, Tsutomu
Chemistry Letters, 1985 , p. 921 - 924
参考文献
Petrow; Nikischin
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 1233,1236;engl.Ausg.S.1395,1396
