2-羟基-6-甲基苯甲醛合成路线 （共 24 条）
反应条件
1.1: ethanol / 24 h / 25 °C
2.1: n-butyllithium; N,N,N',N,-tetramethylethylenediamine / diethyl ether; hexane / 20 °C / Inert atmosphere
2.2: 12 h
3.1: hydrogenchloride; water / diethyl ether; hexane / 1 h / Inert atmosphere
View Scheme
参考文献
Coulter, Matthew M.; Kou, Kevin G. M.; Galligan, Baye; Dong, Vy M.
Journal of the American Chemical Society, 2010 , vol. 132, # 46 p. 16330 - 16333
参考文献
Fries; Klostermann
Chemische Berichte, 1906 , vol. 39, p. 872,1942
Full Text Show Details
Chuit; Bolsing
Bulletin de la Societe Chimique de France, 1906 , vol. <3> 35, p. 142
反应条件
hydrogenchloride; sodium nitrite
anschliessenden Einleiten von Wasserdampf;
参考文献
Akroyd et al.
Journal of the Chemical Society, 1954 , p. 286,290
Journal of the Chemical Society, 1951 , p. 3427
反应条件
1: P2O5 / Behandeln mit KOH und dann mit Wasser
2: NaOH-solution
View Scheme
参考文献
Tiemann; Schotten
Chemische Berichte, 1878 , vol. 11, p. 769
反应条件
alkali
Nebenprod.2: 2-Oxy-4-methyl-benzaldehyd;
参考文献
Hodgson; Jenkinson
Journal of the Chemical Society, 1929 , p. 469,470
反应条件
alkali
Nebenprod.2: 2-Oxy-4-methyl-benzaldehyd;
参考文献
Hodgson; Jenkinson
Journal of the Chemical Society, 1929 , p. 469,470
反应条件
sodium hydroxide
6 h; Heating;
参考文献
Chatterjea, J. N.; Singh, K. R. R. P.; Jha, I. S.; Prasad, Y.; Shaw, S. C.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1986 , vol. 25, p. 796 - 798
参考文献
Fries; Klostermann
Chemische Berichte, 1906 , vol. 39, p. 874
Justus Liebigs Annalen der Chemie, 1908 , vol. 362, p. 13
Full Text Show Details
Auwers; Keil
Chemische Berichte, 1902 , vol. 35, p. 4215
Full Text Show Details
Tiemann; Schotten
Chemische Berichte, 1878 , vol. 11, p. 769
Full Text Show Details
Chuit; Bolsing
Bulletin de la Societe Chimique de France, 1906 , vol. <3> 35, p. 142
参考文献
Love
J. roy. tech. Coll., 1935 , vol. 3, p. 385
参考文献
Fries; Klostermann
Chemische Berichte, 1906 , vol. 39, p. 874
Justus Liebigs Annalen der Chemie, 1908 , vol. 362, p. 13
Full Text Show Details
Auwers; Keil
Chemische Berichte, 1902 , vol. 35, p. 4215
Full Text Show Details
Tiemann; Schotten
Chemische Berichte, 1878 , vol. 11, p. 769
Full Text Show Details
Chuit; Bolsing
Bulletin de la Societe Chimique de France, 1906 , vol. <3> 35, p. 142
